{"refrec":{"BRefID":142004,"RR":"<b>Reinhard, C.T.; Raiswell, R.; Scott, C.; Anbar, A.D.; Lyons, T.W.</b> (2009). A Late Archean sulfidic sea stimulated by early oxidative weathering of the continents. <i>Science (Wash.) 326(5953)</i>: 713-716. <a href=\"https://dx.doi.org/10.1126/science.1176711\" target=\"_blank\">https://dx.doi.org/10.1126/science.1176711</a>","BEntID":135260,"PublicFlag":1,"CheckedFlag":1,"wosflag":1,"vabbflag":1,"RefStringPartII":". <i>Science (Wash.) 326(5953)</i>: 713-716. <a href=\"https://dx.doi.org/10.1126/science.1176711\" target=\"_blank\">https://dx.doi.org/10.1126/science.1176711</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":1,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Reinhard, C.T.; Raiswell, R.; Scott, C.; Anbar, A.D.; Lyons, T.W.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Reinhard, C.T. <i>et al.</i>","Englishabstract":"Iron speciation data for the late Archean Mount McRae Shale provide evidence for a euxinic (anoxic and sulfidic) water column 2.5 billion years ago. Sulfur isotope data compiled from the same stratigraphic section suggest that euxinic conditions were stimulated by an increase in oceanic sulfate concentrations resulting from weathering of continental sulfide minerals exposed to an atmosphere with trace amounts of photosynthetically produced oxygen. Variability in local organic matter flux likely confined euxinic conditions to midportions of the water column on the basin margin. 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