{"refrec":{"BRefID":195627,"RR":"<b>Harrington, M.J.; Masic, A.; Holten-Andersen, N.; Waite, J.H.; Fratzl, P.</b> (2010). Iron-clad fibers: a metal-based biological strategy for hard flexible coatings. <i>Science (Wash.) 328(5975)</i>: 216-220. <a href=\"https://dx.doi.org/10.1126/science.1181044\" target=\"_blank\">https://dx.doi.org/10.1126/science.1181044</a>","BEntID":188095,"PublicFlag":1,"CheckedFlag":1,"wosflag":1,"vabbflag":1,"RefStringPartII":". <i>Science (Wash.) 328(5975)</i>: 216-220. <a href=\"https://dx.doi.org/10.1126/science.1181044\" target=\"_blank\">https://dx.doi.org/10.1126/science.1181044</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":1,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Harrington, M.J.; Masic, A.; Holten-Andersen, N.; Waite, J.H.; Fratzl, P.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Harrington, M.J. <i>et al.</i>","Englishabstract":"The extensible byssal threads of marine mussels are shielded from abrasion in wave-swept habitats by an outer cuticle that is largely proteinaceous and approximately fivefold harder than the thread core. Threads from several species exhibit granular cuticles containing a protein that is rich in the catecholic amino acid 3,4-dihydroxyphenylalanine (dopa) as well as inorganic ions, notably Fe3+. Granular cuticles exhibit a remarkable combination of high hardness and high extensibility. We explored byssus cuticle chemistry by means of in situ resonance Raman spectroscopy and demonstrated that the cuticle is a polymeric scaffold stabilized by catecholato-iron chelate complexes having an unusual clustered distribution. Consistent with byssal cuticle chemistry and mechanics, we present a model in which dense cross-linking in the granules provides hardness, whereas the less cross-linked matrix provides extensibility.","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Iron-clad fibers: a metal-based biological strategy for hard flexible coatings","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2026-05-24 01:31:14.883759","timezone_type":1,"timezone":"+02:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":null,"OtherDescriptors":null,"Notes":null,"AnaPub":2010,"MonPub":null,"DateUpdate":"2018-02-13","DateCreate":"2010-05-28","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000276459600039","VABBcode":null,"OpenAcc":0,"DOI":"10.1126/science.1181044"},"refs":null,"anarec":{"AnaID":195627,"PubliDate":2010,"Pagination":"216-220","XtraPublOfAnaID":null,"ISBN":null,"Volume":"328","Issue":"5975","BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":43776,"SerRR":"Science (Washington). 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