{"refrec":{"BRefID":198580,"RR":"<b>Chen, M.; Schliep, M.; Willows, R.D.; Cai, Z.-L.; Neilan, B.A.; Scheer, H.</b> (2010). A red-shifted chlorophyll. <i>Science (Wash.) 329(5997)</i>: 1318-1319. <a href=\"https://dx.doi.org/10.1126/science.1191127\" target=\"_blank\">https://dx.doi.org/10.1126/science.1191127</a>","BEntID":190899,"PublicFlag":1,"CheckedFlag":1,"wosflag":1,"vabbflag":1,"RefStringPartII":". <i>Science (Wash.) 329(5997)</i>: 1318-1319. <a href=\"https://dx.doi.org/10.1126/science.1191127\" target=\"_blank\">https://dx.doi.org/10.1126/science.1191127</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":1,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Chen, M.; Schliep, M.; Willows, R.D.; Cai, Z.-L.; Neilan, B.A.; Scheer, H.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Chen, M. <i>et al.</i>","Englishabstract":"Chlorophylls are essential for light-harvesting and energy transduction in photosynthesis. Four chemically distinct varieties have been known for the past 60 years. Here we report isolation of a fifth, which we designate chlorophyll f. Its in vitro absorption (706 nanometers) and fluorescence (722 nanometers) maxima are red-shifted compared to all other chlorophylls from oxygenic phototrophs. On the basis of the optical, mass, and nuclear magnetic resonance spectra, we propose that chlorophyll f is [2-formyl]-chlorophyll a (C(55)H(70)O(6)N(4)Mg). 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