Document of bibliographic reference 199471

BibliographicReference record

Type
Bibliographic resource
Type of document
Journal article
BibLvlCode
AS
Title
Validation and application of an LC-MS/MS method for the simultaneous quantification of 13 pharmaceuticals in seawater
Abstract
Knowledge of the presence of micropollutants such as pharmaceuticals, in coastal areas, is very limited; therefore, the main objective of this study was to optimize and validate a new analytical method for the quantitative analysis of 13 multiclass pharmaceuticals in seawater. Target compounds included antibiotics, non-steroidal anti-inflammatory drugs, beta-blockers, lipid regulators and one psychiatric drug. A combination of solid-phase extraction and liquid chromatography coupled with multiple mass spectrometry enabled their detection at the low nanogram per litre level. The limits of quantification varied between 1 and 50 ng L(-1), for most components the linearities were more than 0.99 and the recoveries obtained in seawater (95-108%) were satisfactory. This method was applied to seawater and estuarine water samples collected in the Belgian coastal zone, to assess the prevalence of common pharmaceuticals in this marine environment. Seven phar-maceuticals, including compounds of which the presence in marine environments had not been reported earlier, were detected, with salicylic acid and carbamazepine being the most abundant, in concentrations up to 855 ng L(-1).
WebOfScience code
https://www.webofscience.com/wos/woscc/full-record/WOS:000278810000022
Bibliographic citation
Wille, K.; Noppe, H.; Verheyden, K.; Vanden Bussche, J.; De Wulf, E.; Van Caeter, P.; Janssen, C.R.; De Brabander, H.F.; Vanhaecke, L. (2010). Validation and application of an LC-MS/MS method for the simultaneous quantification of 13 pharmaceuticals in seawater. Anal. Bioanal. Chem. 397(5): 1797-1808. dx.doi.org/10.1007/s00216-010-3702-z
Topic
Marine
Is peer reviewed
true

Authors

author
Name
Klaas Wille
Affiliation
Universiteit Gent; Faculteit Diergeneeskunde; Vakgroep Veterinaire Volksgezondheid & Voedselveiligheid; Laboratorium voor Chemische Analyse
author
Name
Herlinde Noppe
Affiliation
Universiteit Gent; Faculteit Diergeneeskunde; Vakgroep Veterinaire Volksgezondheid & Voedselveiligheid; Laboratorium voor Chemische Analyse
author
Name
Karolien Verheyden
Affiliation
Universiteit Gent; Faculteit Diergeneeskunde; Vakgroep Veterinaire Volksgezondheid & Voedselveiligheid; Laboratorium voor Chemische Analyse
author
Name
Julie Vanden Bussche
Identifier
https://orcid.org/0000-0002-3831-6663
Affiliation
Universiteit Gent; Faculteit Diergeneeskunde; Vakgroep Veterinaire Volksgezondheid & Voedselveiligheid; Laboratorium voor Chemische Analyse
author
Name
Eric De Wulf
author
Name
Peter Van Caeter
author
Name
Colin Janssen
Identifier
https://orcid.org/0000-0002-7781-6679
Affiliation
Universiteit Gent; Faculteit Bio-ingenieurswetenschappen; Vakgroep Dierwetenschappen en Aquatische Ecologie; Laboratorium voor Milieutoxicologie
author
Name
Hubert De Brabander
Affiliation
Universiteit Gent; Faculteit Diergeneeskunde; Vakgroep Veterinaire Volksgezondheid & Voedselveiligheid; Laboratorium voor Chemische Analyse
author
Name
Lynn Vanhaecke
Identifier
https://orcid.org/0000-0003-0400-2188
Affiliation
Universiteit Gent; Faculteit Diergeneeskunde; Vakgroep Veterinaire Volksgezondheid & Voedselveiligheid; Laboratorium voor Chemische Analyse

Links

referenced creativework
type
DOI
accessURL
https://dx.doi.org/10.1007/s00216-010-3702-z

thesaurus terms

term
Marine environment (term code: 4999 - defined in term set: ASFA Thesaurus List)
Persistence (term code: 6093 - defined in term set: ASFA Thesaurus List)
Pharmaceuticals (term code: 64129 - defined in term set: CSA Technology Research Database Master Thesaurus)
Validation (term code: 54572 - defined in term set: CSA Technology Research Database Master Thesaurus)

Other terms

other terms associated with this publication
Liquid chromatography– tandem mass spectrometry

Document metadata

date created
2010-10-19
date modified
2014-10-09