{"refrec":{"BRefID":210928,"RR":"<b>Gillikin, D.P.; Lorrain, A.; Meng, L.; Dehairs, F.</b> (2007). A large metabolic carbon contribution to the d<sup>13</sup>C record in marine aragonitic bivalve shells. <i>Geochim. Cosmochim. Acta 71(12)</i>: 2936-2946. <a href=\"http://dx.doi.org/10.1016/j.gca.2007.04.003\" target=\"_blank\">dx.doi.org/10.1016/j.gca.2007.04.003</a>","BEntID":202850,"PublicFlag":1,"CheckedFlag":1,"wosflag":1,"vabbflag":1,"RefStringPartII":". <i>Geochim. Cosmochim. Acta 71(12)</i>: 2936-2946. <a href=\"https://dx.doi.org/10.1016/j.gca.2007.04.003\" target=\"_blank\">https://dx.doi.org/10.1016/j.gca.2007.04.003</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":1,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Gillikin, D.P.; Lorrain, A.; Meng, L.; Dehairs, F.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Gillikin, D.P. <i>et al.</i>","Englishabstract":"It is well known that the incorporation of isotopically light metabolic carbon (C<sup>M</sup>) significantly affects the stable carbon isotope (d<sup>13</sup>C) signal recorded in biogenic carbonates. This can obscure the record of d<sup>13</sup>C of seawater dissolved inorganic carbon (d<sup>13</sup>C<sub>DIC</sub>) potentially archived in the shell carbonate. To assess the C<sub>M</sub> contribution to <i>Mercenaria mercenaria</i> shells collected in North Carolina, USA, we sampled seawater d<sup>13</sup>C<sub>DIC</sub>, tissue, hemolymph and shell d<sup>13</sup>C. All shells showed an ontogenic decrease in shell d<sup>13</sup>C, with as much as a 4%. decrease over the lifespan of the clam. There was no apparent ontogenic change in food source indicated by soft tissue d<sup>13</sup>C values, therefore a change in the respired d<sup>13</sup>C value cannot be the cause of this decrease. Hemolymph d<sup>13</sup>C, on the other hand, did exhibit a negative relationship with shell height indicating that respired CO<sub>2</sub> does influence the d<sup>13</sup>C value of internal fluids and that the amount of respired CO<sub>2</sub> is related to the size or age of the bivalve. The percent metabolic C incorporated into the shell (%C-M) was significantly higher (up to 37%, with a range from 5% to 37%) than has been found in other bivalve shells, which usually contain less than 10%C-M. Interestingly, the hemolymph did contain less than 10%C-M, suggesting that complex fractionation might occur between hemolymph and calcifying fluids. Simple shell biometrics explained nearly 60% of the observed variability in %C-M, however, this is not robust enough to predict %C-M for fossil shells. Thus, the metabolic effect on shell d<sup>13</sup>C cannot easily be accounted for to allow reliable d<sup>13</sup>C<sub>DIC</sub> reconstructions. However, there does seem to be a common effect of size, as all sites had indistinguishable slopes between the %C<sub>M</sub> and shell height (+0.19% per mm of shell height).","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"A large metabolic carbon contribution to the d<sup>13</sup>C record in marine aragonitic bivalve shells","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2024-12-10 01:32:52.928458","timezone_type":1,"timezone":"+01:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":null,"OtherDescriptors":null,"Notes":null,"AnaPub":2007,"MonPub":null,"DateUpdate":"2012-01-17","DateCreate":"2011-12-22","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000247216400002","VABBcode":null,"OpenAcc":0,"DOI":"10.1016/j.gca.2007.04.003"},"refs":null,"anarec":{"AnaID":210928,"PubliDate":2007,"Pagination":"2936-2946","XtraPublOfAnaID":null,"ISBN":null,"Volume":"71","Issue":"12","BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":42901,"SerRR":"Geochimica et Cosmochimica Acta. Elsevier: Oxford,New York etc..  ISSN 0016-7037; e-ISSN 1872-9533","StandardTitleSer":"Geochimica et Cosmochimica Acta","ISSN":"0016-7037","AbbrevSer":"Geochim. Cosmochim. 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