{"refrec":{"BRefID":221897,"RR":"<b>Charles, S.; Yunus, S.; Dubois, F.; Vander Donckt, E.</b> (2001). Determination of cadmium in marine waters: on-line preconcentration and flow-through fluorescence detection. <i>Anal. Chim. Acta 440(1)</i>: 37-43. <a href=\"http://dx.doi.org/10.1016/S0003-2670(01)00857-1\" target=\"_blank\">http://dx.doi.org/10.1016/S0003-2670(01)00857-1</a>","BEntID":213624,"PublicFlag":1,"CheckedFlag":0,"wosflag":1,"vabbflag":1,"RefStringPartII":". <i>Anal. Chim. Acta 440(1)</i>: 37-43. <a href=\"http://dx.doi.org/10.1016/S0003-2670(01)00857-1\" target=\"_blank\">http://dx.doi.org/10.1016/S0003-2670(01)00857-1</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":1,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Charles, S.; Yunus, S.; Dubois, F.; Vander Donckt, E.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Charles, S. <i>et al.</i>","Englishabstract":"This paper reports the development of a new molecular fluorescence spectroscopy method for the determination of cadmium in marine waters. An anthrylhexaazamacrocycle was used as a fluorogenic reagent at pH 13. Ionic extraction chromatography on Dowex resin was necessary to separate cadmium from the matrix and especially from lead, mercury and organic matters present in seawater and interfering with the fluorescence measurements. The coupling of on-line preconcentration by Dowex resin and fluorescence flow-through detection at pH 13 led to a detection limit of 35 pM for a preconcentration time of 5 min (2.1 ml min<sup>-1</sup>). The accuracy of the method was verified on certified seawater samples SLEW-2 and NASS-5. Water samples collected in the Scheldt estuary near Antwerp (Belgium) during an ebb tide were analysed for dissolved cadmium.","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Determination of cadmium in marine waters: on-line preconcentration and flow-through fluorescence detection","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2026-06-09 01:31:25.672042","timezone_type":1,"timezone":"+02:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":"    Cadmium;     On-line preconcentration;     Molecular fluorescence spectroscopy;     Seawater;     Anthrylazamacrocycle;     Fluorogenic reagent","OtherDescriptors":null,"Notes":null,"AnaPub":2001,"MonPub":null,"DateUpdate":"2015-11-04","DateCreate":"2013-01-10","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000170243600005","VABBcode":null,"OpenAcc":0,"DOI":"10.1016/S0003-2670(01)00857-1"},"refs":null,"anarec":{"AnaID":221897,"PubliDate":2001,"Pagination":"37-43","XtraPublOfAnaID":null,"ISBN":null,"Volume":"440","Issue":"1","BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":42099,"SerRR":"Analytica Chimica Acta. Elsevier: New York; Amsterdam.  ISSN 0003-2670; e-ISSN 1873-4324","StandardTitleSer":"Analytica Chimica Acta","ISSN":"0003-2670","AbbrevSer":"Anal. Chim. Acta","StandardTitleMon":null,"StartPage":37,"Pages":7,"ToPubliDate":null,"BRefBibLvlCode":"S","SerNotes":null},"monrec":null,"serrec":null,"relations":null,"relationsRev":null,"addrec":null,"othpubs":null,"ownerships":null,"authors":[{"AutName":"Charles","Firstname":null,"Initials":"S.","Affiliation":"Laboratoire de Chimie Organique Physique CP 160/08, Université Libre de Bruxelles","Discriminator":null,"CorporateFlag":0,"BEntID":213624,"AutID":157112,"OrderNr":1,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"ORG","InsFSN":"Université Libre de Bruxelles; Faculté des Sciences; Chimie organique","ORCID":null,"PersID":null,"InsID":181},{"AutName":"Yunus","Firstname":null,"Initials":"S.","Affiliation":"Laboratoire de Chimie Organique Physique CP 160/08, Université Libre de Bruxelles","Discriminator":null,"CorporateFlag":0,"BEntID":213624,"AutID":157113,"OrderNr":2,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"ORG","InsFSN":"Université Libre de Bruxelles; Faculté des Sciences; Chimie organique","ORCID":null,"PersID":null,"InsID":181},{"AutName":"Dubois","Firstname":null,"Initials":"F.","Affiliation":"Laboratoire de Chimie Organique Physique CP 160/08, Université Libre de Bruxelles","Discriminator":null,"CorporateFlag":0,"BEntID":213624,"AutID":157114,"OrderNr":3,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"ORG","InsFSN":"Université Libre de Bruxelles; Faculté des Sciences; Chimie organique","ORCID":null,"PersID":null,"InsID":181},{"AutName":"Vander Donckt","Firstname":null,"Initials":"E.","Affiliation":"Laboratoire de Chimie Organique Physique CP 160/08, Université Libre de Bruxelles","Discriminator":null,"CorporateFlag":0,"BEntID":213624,"AutID":157115,"OrderNr":4,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"ORG","InsFSN":"Université Libre de Bruxelles; Faculté des Sciences; Chimie organique","ORCID":null,"PersID":null,"InsID":181}],"mapdetails":null,"datasets":null,"monographs":null,"monparts":null,"serparts":null,"BEntOpen":null,"BEntPrivate":null,"availability":[{"BInstID":273728,"LibID":36,"BRefID":221897,"EmbargoDate":null,"FullEmbargoDate":null,"PhysMedID":16,"hasOCRd":1,"ShelfLocCode":"273728","RFID":null,"PaidValue":null,"Medium":"Server","Description":null,"Acronym":"VLIZ","Library":"Vlaams Instituut voor de Zee","DutchTerm":"Open Marien Archief","URL":null,"ClassifID":235,"Classification":"Open Marine Archive","ReqLink":null,"ClassifTypID":5,"URLLocation":"https://www.vliz.be/imisdocs/publications/","SubDir":0,"InternalReq":0,"LoggedInReq":0,"Disclaimer":"Disclaimer_OMA","DutchDisclaimer":null,"FileFormat":".pdf","FileDescr":"pdf","InsPub":1,"InsID":36,"FileFormID":6,"LendableFlag":1,"PublicFlag":1,"orderLib":"A","Notes":null,"AccConID":null,"AccessConstraint":null,"LicURL":null}],"litstyles":null,"thespers":null,"arch2discl":null,"SERpubls":[{"PublName":"Elsevier","City":"New York; Amsterdam"}],"MONpubls":null,"pictures":[],"thestermsPath":null,"thestermsASFA":null,"taxtermsASFA":null,"geotermsASFA":null,"collections":[{"Collection":"OMA - Open Marien Archief","ShortName":"OMA"},{"Collection":"ScheldeMonitor","ShortName":"scheldemonitor"}],"conf":null,"proj":null,"Physdatasets":null,"spcols":{"222":{"SpName":"BMB - Belgische Mariene Bibliografie","SpColID":222,"ParSpColID":null,"TopParID":null,"ShortName":"BMB","URLLocation":null,"LibID":36,"OpenRepoFlag":null,"SpTypID":null,"TopParIDNotWebsite":null,"SpColPath":"BMB"},"867":{"SpName":"IMIS themes","SpColID":867,"ParSpColID":null,"TopParID":null,"ShortName":"IMIS themes","URLLocation":null,"LibID":null,"OpenRepoFlag":null,"SpTypID":null,"TopParIDNotWebsite":null,"SpColPath":"IMIS themes"},"52":{"SpName":"Methods and techniques","SpColID":52,"ParSpColID":867,"TopParID":867,"ShortName":"Methodes en technieken","URLLocation":null,"LibID":null,"OpenRepoFlag":null,"SpTypID":null,"TopParIDNotWebsite":867,"SpColPath":"IMIS themes/Methodes en technieken"},"221":{"SpName":"OMA - Open Marien Archief","SpColID":221,"ParSpColID":null,"TopParID":null,"ShortName":"OMA","URLLocation":null,"LibID":36,"OpenRepoFlag":1,"SpTypID":null,"TopParIDNotWebsite":null,"SpColPath":"OMA"},"639":{"SpName":"Physics and chemistry","SpColID":639,"ParSpColID":867,"TopParID":867,"ShortName":"Fysicochemie","URLLocation":null,"LibID":null,"OpenRepoFlag":null,"SpTypID":null,"TopParIDNotWebsite":867,"SpColPath":"IMIS themes/Fysicochemie"},"27":{"SpName":"ScheldeMonitor","SpColID":27,"ParSpColID":null,"TopParID":null,"ShortName":"scheldemonitor","URLLocation":null,"LibID":null,"OpenRepoFlag":null,"SpTypID":null,"TopParIDNotWebsite":null,"SpColPath":"scheldemonitor"}},"doi":null,"publs":null,"serparttypes":null,"monauthors":null,"MParts":null,"SParts":null,"hLibs":null,"langs":[{"BEntID":213624,"AbstractFlag":0,"LangID":15,"LangCode":"en","Lang":"English","DutchTerm":"Engels","LangCodeExtended":"eng"},{"BEntID":213624,"AbstractFlag":1,"LangID":15,"LangCode":"en","Lang":"English","DutchTerm":"Engels","LangCodeExtended":"eng"}],"urls":[{"URL":"http://dx.doi.org/10.1016/S0003-2670(01)00857-1","externalID":"10.1016/S0003-2670(01)00857-1","URLTypeCode":"DOI","URLID":25240,"URLTypID":13,"URLType":"DOI","URLPrefix":"http://dx.doi.org/"}],"thesterms":null,"taxterms":null,"geoterms":null,"othterms":null,"asfacodes":null,"asfa2codes":null,"thestermsFRIS":null,"taxtermsFRIS":null,"geotermsFRIS":null,"othtermsFRIS":null,"resmessage":"","complete":1,"sessions":{"newSesName":"Bouchti, Zohra, Z.","newSesDate":{"date":"2013-01-10 13:44:18.113000","timezone_type":3,"timezone":"Europe/Brussels"},"updSesName":"Bouchti, Zohra, Z.","updSesDate":{"date":"2015-11-04 08:38:56.913000","timezone_type":3,"timezone":"Europe/Brussels"}}}