{"refrec":{"BRefID":224026,"RR":"<b>Amouroux, D.; Tessier, E.; Donard, O.F.X.</b> (2000). Volatilization of organotin compounds from estuarine and coastal environments. <i>Environ. Sci. Technol. 34(6)</i>: 988-995. <a href=\"http://dx.doi.org/10.1021/es981025p\" target=\"_blank\">http://dx.doi.org/10.1021/es981025p</a>","BEntID":215749,"PublicFlag":1,"CheckedFlag":0,"wosflag":1,"vabbflag":1,"RefStringPartII":". <i>Environ. Sci. Technol. 34(6)</i>: 988-995. <a href=\"http://dx.doi.org/10.1021/es981025p\" target=\"_blank\">http://dx.doi.org/10.1021/es981025p</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":0,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Amouroux, D.; Tessier, E.; Donard, O.F.X.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Amouroux, D. <i>et al.</i>","Englishabstract":"The occurrence and speciation of volatile tin compounds (Sn) have been investigated in a contaminated area of the Arcachon Bay (SW France) and in the water column of the Scheldt (Belgium/Netherlands) and Gironde (SW France) estuaries. This paper describes the application of a multi-isotope analytical method, using gas chromatography and inductively coupled plasma-mass spectrometry. Analytes were collected by cryogenic trapping of the gaseous species. This trapping has allowed us to probe volatile tin compounds by detecting both <sup>118</sup>Sn and <sup>120</sup>Sn isotopes. Volatile organic tin compounds have been determined in both sediment and water. They could result from both natural methylation and hydridization processes of inorganic tin (R<i><sub>n</sub></i>R‘<sub>4</sub><sub>-</sub><i><sub>n</sub></i>Sn; R = Me, R‘ = H, <i>n</i> = 0-4) and from anthropogenic butyltin derivatives released from ship antifouling paintings which have accumulated in sediments (R<i><sub>n</sub></i>R‘<sub>4</sub><sub>-</sub><sub>n</sub> Sn; R = Bu, R‘ = H or Me, <i>n</i> = 0-3). The most ubiquitous species were found to be the methylated forms of butyltin derivatives (Bu<i><sub>n</sub></i>SnMe<sub>4</sub><sub>-</sub><i><sub>n</sub></i>, <i>n</i> = 0-3). These results suggest that biological and/or chemical methylation mechanisms are likely to occur in sediments and to lead to remobilization of tin species into the water column and subsequently to the atmosphere. Finally, sediment-water and water-atmosphere fluxes have been calculated to assess the potential impact of these processes on the fate of organotin compounds in coastal environments.","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Volatilization of organotin compounds from estuarine and coastal environments","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2026-04-24 01:31:58.717627","timezone_type":1,"timezone":"+02:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":null,"OtherDescriptors":null,"Notes":null,"AnaPub":2000,"MonPub":null,"DateUpdate":"2015-12-01","DateCreate":"2013-03-26","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000085867400010","VABBcode":null,"OpenAcc":0,"DOI":"10.1021/es981025p"},"refs":null,"anarec":{"AnaID":224026,"PubliDate":2000,"Pagination":"988-995","XtraPublOfAnaID":null,"ISBN":null,"Volume":"34","Issue":"6","BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":42837,"SerRR":"Environmental Science and Technology. 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