{"refrec":{"BRefID":224039,"RR":"Ceulemans, M.; Szpunar-lobinska, J.; Dirkx, W.M.R.; lobinski, R.; Adams, F.C. (1993). Speciation analysis of organotin in the river Scheldt by capillary Gas chromatography Atomic emission spectrometry (Gc-Aes). Int. J. Environ. Anal. Chem. 52(1-4): 113-125. http://dx.doi.org/10.1080/03067319308042853","BEntID":215762,"PublicFlag":1,"CheckedFlag":0,"wosflag":1,"vabbflag":1,"RefStringPartII":". Int. J. Environ. Anal. Chem. 52(1-4): 113-125. http://dx.doi.org/10.1080/03067319308042853","DocTypID":8,"DocType":"Journal article","MarineFlag":0,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Ceulemans, M.; Szpunar-lobinska, J.; Dirkx, W.M.R.; lobinski, R.; Adams, F.C.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Ceulemans, M. et al.","Englishabstract":"Two rapid, sensitive and interference-free analytical procedures were developed for the comprehensive speciation analysis of ionic butyl- and phenyltin compounds in water. One of them based on ethylation of ionic organotin in the aqueous phase with sodium tetraethylborate (NaBEt4) followed by the extraction of the derivatized species into hexane. The other method involved preconcentration of ionic organotin on a C18 cartridge followed by on-column ethylation in a semi-automated flow system. Separation and determination of organotin species were performed by capillary gas chromatography with microwave induced plasma atomic emission detection (GC-MIP AED). 20–50 ml of sample was sufficient for the analysis and a detection limit of 0.1 ng/l (as Sn) was obtained. The methods were applied to the determination of organotin in the river Scheldt at 15 locations close to the Antwerp agglomeration. Butyltin compounds were detected in all the analyzed samples at concentrations ranging between 10–140 ng/l, 8–70 ng/l and 4–10 ng/l for the mono-, di- and tributyltin in the dissolved phase, respectively. No phenyltin species were detected. The agreement between the results obtained by different methods was within 15%.","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Speciation analysis of organotin in the river Scheldt by capillary Gas chromatography Atomic emission spectrometry (Gc-Aes)","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2026-04-24 01:31:58.733252","timezone_type":1,"timezone":"+02:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":" Speciation, organotin, water analysis, liquid-liquid extraction, solid phase extraction, GC-AED","OtherDescriptors":null,"Notes":null,"AnaPub":1993,"MonPub":null,"DateUpdate":"2016-12-08","DateCreate":"2013-03-26","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:A1993LR74200011","VABBcode":null,"OpenAcc":0,"DOI":"10.1080/03067319308042853"},"refs":null,"anarec":{"AnaID":224039,"PubliDate":1993,"Pagination":"113-125","XtraPublOfAnaID":null,"ISBN":null,"Volume":"52","Issue":"1-4","BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":43159,"SerRR":"International journal of environmental and analytical chemistry. Taylor & Francis: Amsterdam. ISSN 0306-7319; e-ISSN 1029-0397","StandardTitleSer":"International journal of environmental and analytical chemistry","ISSN":"0306-7319","AbbrevSer":"Int. J. Environ. Anal. Chem.","StandardTitleMon":null,"StartPage":113,"Pages":13,"ToPubliDate":null,"BRefBibLvlCode":"S","SerNotes":null},"monrec":null,"serrec":null,"relations":null,"relationsRev":null,"addrec":null,"othpubs":null,"ownerships":null,"authors":[{"AutName":"Ceulemans","Firstname":null,"Initials":"M.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":215762,"AutID":32710,"OrderNr":1,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null},{"AutName":"Szpunar-lobinska","Firstname":null,"Initials":"J.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":215762,"AutID":159825,"OrderNr":2,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null},{"AutName":"Dirkx","Firstname":null,"Initials":"W.M.R.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":215762,"AutID":159826,"OrderNr":3,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null},{"AutName":"lobinski","Firstname":null,"Initials":"R.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":215762,"AutID":159827,"OrderNr":4,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null},{"AutName":"Adams","Firstname":null,"Initials":"F.C.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":215762,"AutID":46450,"OrderNr":5,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":806,"InsID":null}],"mapdetails":null,"datasets":null,"monographs":null,"monparts":null,"serparts":null,"BEntOpen":null,"BEntPrivate":null,"availability":[{"BInstID":297150,"LibID":36,"BRefID":224039,"EmbargoDate":null,"FullEmbargoDate":null,"PhysMedID":16,"hasOCRd":1,"ShelfLocCode":"297150","RFID":null,"PaidValue":null,"Medium":"Server","Description":"Interne VLIZ documenten","Acronym":"VLIZ","Library":"Vlaams Instituut voor de Zee","DutchTerm":"Non-open access","URL":null,"ClassifID":228,"Classification":"Non-open access","ReqLink":1,"ClassifTypID":3,"URLLocation":"https://www.vliz.be/imisdocs/publications/","SubDir":1,"InternalReq":1,"LoggedInReq":1,"Disclaimer":"Disclaimer_VLIZ_Intern","DutchDisclaimer":"
Deze publicatie is enkel beschikbaar voor persoonlijk gebruik binnen de Innovocean site en mag op geen enkele manier verder worden verspreid.