{"refrec":{"BRefID":23574,"RR":"<b>Bakker, R.J.</b> (1998). Improvements in clathrate modelling II: the H<sub>2</sub>O-CO<sub>2</sub>-CH<sub>4</sub>-N<sub>2</sub>-C<sub>2</sub>H<sub>6</sub> fluid system, <b><i>in</i></b>: Henriet, J.-P. <i>et al.</i> <i>Gas hydrates: relevance to world margin stability and climate change. Geological Society Special Publication,</i> 137: pp. 75-105. <a href=\"https://dx.doi.org/10.1144/GSL.SP.1998.137.01.06\" target=\"_blank\">https://dx.doi.org/10.1144/GSL.SP.1998.137.01.06</a>","BEntID":23574,"PublicFlag":1,"CheckedFlag":0,"wosflag":0,"vabbflag":0,"RefStringPartII":", <b><i>in</i></b>: Henriet, J.-P. <i>et al.</i> <i>Gas hydrates: relevance to world margin stability and climate change. Geological Society Special Publication,</i> 137: pp. 75-105. <a href=\"https://dx.doi.org/10.1144/GSL.SP.1998.137.01.06\" target=\"_blank\">https://dx.doi.org/10.1144/GSL.SP.1998.137.01.06</a>","DocTypID":17,"DocType":"Book chapters","MarineFlag":1,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Bakker, R.J.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Bakker, R.J.","Englishabstract":"Clathrate stability conditions have been modelled for the H<sub>2</sub>O-CO<sub>2</sub>-CH<sub>4</sub>-N<sub>2</sub>-C<sub>2</sub>H<sub>6</sub> fluid system based on all available experimental data. Optimum Kihara parameters are estimated for pure CO<sub>2</sub>, CH<sub>4</sub>, N<sub>2</sub> and C<sub>2</sub>H<sub>6</sub> gas hydrates from using the most accurate calculation of other parameters involved in clathrate modelling, like fugacities, gas solubilities in H<sub>2</sub>O and thermodynamic constants. For mixed gas hydrates of CO<sub>2</sub>-CH<sub>4</sub>, CH<sub>4</sub>-N<sub>2</sub>, and CH<sub>4</sub>-C<sub>2</sub>H<sub>6</sub> excess Gibbs free energy functions are introduced to obtain a good fit to experimental data. The excess Gibbs free energy is described according a modified Margules equation, which depends on mole fraction and temperature.","AbstractOtherLang":null,"BibLvlCode":"AMS","StandardTitle":"Improvements in clathrate modelling II: the H<sub>2</sub>O-CO<sub>2</sub>-CH<sub>4</sub>-N<sub>2</sub>-C<sub>2</sub>H<sub>6</sub> fluid system","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2024-12-10 01:33:17.368041","timezone_type":1,"timezone":"+01:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":null,"OtherDescriptors":"clathrate modelling, fluid system","Notes":null,"AnaPub":1998,"MonPub":null,"DateUpdate":"2022-03-22","DateCreate":"2002-03-21","SecASFANote":null,"ConfID":null,"PeerRev":0,"VlizCoreFlag":1,"WoScode":null,"VABBcode":null,"OpenAcc":0,"DOI":"10.1144/GSL.SP.1998.137.01.06"},"refs":null,"anarec":{"AnaID":23574,"PubliDate":1998,"Pagination":"75-105","XtraPublOfAnaID":null,"ISBN":"1-86239-010-X","Volume":"137","Issue":null,"BRefMon":23545,"BRefMonRR":"<b>Henriet, J.-P.; Mienert, J.</b> (1998). Gas hydrates: Relevance to world margin stability and climate change. <i>Geological Society Special Publication</i>, 137. The Geological Society: London. ISBN 1-86239-010-X. 338 pp.","BRefXtra":null,"BRefXtraRR":null,"SerBRefID":5898,"SerRR":"<b>Hartley, A.J. <i>et al.</i> (Ed.)</b> Geological Society Special Publication. Geological Society of London: Oxford; London; Edinburgh; Boston, Mass.; Carlton, Vic..  ISSN 0305-8719; e-ISSN 2041-4927","StandardTitleSer":"Geological Society Special Publication","ISSN":"0305-8719","AbbrevSer":"Geol. Soc. Lond. 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