{"refrec":{"BRefID":285117,"RR":"<b>van Dijk, I.; de Nooijer, L.J.; Boer, W.; Reichart, G.-J.</b> (2017). Sulfur in foraminiferal calcite as a potential proxy for seawater carbonate ion concentration. <i>Earth Planet. Sci. Lett. 470</i>: 64-72. <a href=\"https://dx.doi.org/10.1016/j.epsl.2017.04.031\" target=\"_blank\">https://dx.doi.org/10.1016/j.epsl.2017.04.031</a>","BEntID":277142,"PublicFlag":1,"CheckedFlag":1,"wosflag":1,"vabbflag":1,"RefStringPartII":". <i>Earth Planet. Sci. Lett. 470</i>: 64-72. <a href=\"https://dx.doi.org/10.1016/j.epsl.2017.04.031\" target=\"_blank\">https://dx.doi.org/10.1016/j.epsl.2017.04.031</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":0,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"van Dijk, I.; de Nooijer, L.J.; Boer, W.; Reichart, G.-J.","OrigTitleTranslFlag":0,"Authorstringtrunc":"van Dijk, I. <i>et al.</i>","Englishabstract":"Sulfur (S) incorporation in foraminiferal shells is hypothesized to change with carbonate ion concentration [View the MathML sourceCO32−], due to substitution of sulfate for carbonate ions in the calcite crystal lattice. Hence S/Ca values of foraminiferal carbonate shells are expected to reflect sea water carbonate chemistry. To generate a proxy calibration linking the incorporation of S into foraminiferal calcite to carbonate chemistry, we cultured juvenile clones of the larger benthic species Amphistegina gibbosa and Sorites marginalis over a 350–1200 ppm range of pCO2 values, corresponding to a range in [View the MathML sourceCO32−] of 93 to 211 μmol/kg. We also investigated the potential effect of salinity on S incorporation by culturing juvenile Amphistegina lessonii over a large salinity gradient (25–45). Results show S/CaCALCITE is not impacted by salinity, but increases with increasing pCO2 (and thus decreasing [View the MathML sourceCO32−] and pH), indicating S incorporation may be used as a proxy for [View the MathML sourceCO32−]. Higher S incorporation in high-Mg species S. marginalis suggests a superimposed biomineralization effect on the incorporation of S. Microprobe imaging reveals co-occurring banding of Mg and S in Amphistegina lessonii, which is in line with a strong biological control and might explain higher S incorporation in high Mg species. Provided a species-specific calibration is available, foraminiferal S/Ca values might add a valuable new tool for reconstructing past ocean carbonate chemistry.","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Sulfur in foraminiferal calcite as a potential proxy for seawater carbonate ion concentration","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2024-12-10 01:33:17.368041","timezone_type":1,"timezone":"+01:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":"    foraminifera; sulfur; culture study; carbonate system; intra-test variability","OtherDescriptors":null,"Notes":null,"AnaPub":2017,"MonPub":null,"DateUpdate":"2018-02-13","DateCreate":"2017-05-11","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000402944600007","VABBcode":null,"OpenAcc":1,"DOI":"10.1016/j.epsl.2017.04.031"},"refs":null,"anarec":{"AnaID":285117,"PubliDate":2017,"Pagination":"64-72","XtraPublOfAnaID":null,"ISBN":null,"Volume":"470","Issue":null,"BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":42615,"SerRR":"Earth and Planetary Science Letters. 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