{"refrec":{"BRefID":285545,"RR":"Poma, G.; Malarvannan, G.; Voorspoels, S.; Symons, N.; Malysheva, S.V.; Van Loco, J.; Covaci, A. (2016). Determination of halogenated flame retardants in food: optimization and validation of a method based on a two-step clean-up and gas chromatography-mass spectrometry. Food Control 65: 168-176. https://dx.doi.org/10.1016/j.foodcont.2016.01.027","BEntID":277570,"PublicFlag":1,"CheckedFlag":1,"wosflag":1,"vabbflag":1,"RefStringPartII":". Food Control 65: 168-176. https://dx.doi.org/10.1016/j.foodcont.2016.01.027","DocTypID":8,"DocType":"Journal article","MarineFlag":0,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Poma, G.; Malarvannan, G.; Voorspoels, S.; Symons, N.; Malysheva, S.V.; Van Loco, J.; Covaci, A.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Poma, G. et al.","Englishabstract":"In this work, a new simple method based on a two-step clean-up and gas chromatography mass spectrometry analysis for the determination of emerging halogenated flame retardants (HFRs), such as dechlorane plus (DP) and brominated phthalates, and polybrominated diphenyl ethers (PBDEs) in different food items was optimized and validated. Several types of food items, i.e. fish (smoked salmon and cod fillet), meat (chicken breast), chicken eggs, cow milk, and extra virgin olive oil, were chosen as representative matrices of the main food categories. After lyophilisation, the food samples were extracted using acetonitrile:toluene (9:1, v/v). As interferences, such as lipids and pigments, were co-extracted, a two-step clean-up (including Florisil and acid silica) was performed to efficiently remove them prior to GC MS analysis in electron capture negative ionization mode (GC ECNI/MS). The performance criteria established by the European Commission (2014/118/EU) were achieved with this method for all target analytes, except for the LOQ achieved for BDE-209 (0.1 ng/g wet weight, ww). The trueness ranged between 75 and 125% for most compounds and the matrices analyzed and the repeatability (expressed as RSD%) was <20%, within the set performance criteria. The method was then used for the determination of PBDEs and emerging HFRs in 20 different food items purchased from Antwerp supermarkets, revealing a prevalent contamination with PBDEs (up to 2.02 ng/g ww) and tribromoanisole (up to 6.6 ng/g ww) in the fish/seafood category.","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Determination of halogenated flame retardants in food: optimization and validation of a method based on a two-step clean-up and gas chromatography-mass spectrometry","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2024-12-10 01:33:17.368041","timezone_type":1,"timezone":"+01:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":"PBDEs; Emerging halogenated flame retardants; TBA; Food analysis; Gaschromatography mass spectrometry (GC MS); Food market basket","OtherDescriptors":null,"Notes":null,"AnaPub":2016,"MonPub":null,"DateUpdate":"2022-05-24","DateCreate":"2017-05-16","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000384626500022","VABBcode":null,"OpenAcc":0,"DOI":"10.1016/j.foodcont.2016.01.027"},"refs":null,"anarec":{"AnaID":285545,"PubliDate":2016,"Pagination":"168-176","XtraPublOfAnaID":null,"ISBN":null,"Volume":"65","Issue":null,"BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":220415,"SerRR":"Food Control. Butterworth Scientific/Elsevier: London. ISSN 0956-7135; e-ISSN 1873-7129","StandardTitleSer":"Food Control","ISSN":"0956-7135","AbbrevSer":"Food Control","StandardTitleMon":null,"StartPage":168,"Pages":9,"ToPubliDate":null,"BRefBibLvlCode":"S","SerNotes":null},"monrec":null,"serrec":null,"relations":null,"relationsRev":null,"addrec":null,"othpubs":null,"ownerships":null,"authors":[{"AutName":"Poma","Firstname":"Giulia","Initials":"G.","Affiliation":"Toxicological Center, University of Antwerp","Discriminator":null,"CorporateFlag":0,"BEntID":277570,"AutID":256853,"OrderNr":1,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":"Universiteit Antwerpen; Faculteit Farmaceutische, Biomedische en Diergeneeskundige Wetenschappen; Toxicologisch Centrum","ORCID":"0000-0003-0597-2653","PersID":34524,"InsID":111},{"AutName":"Malarvannan","Firstname":"Govindan","Initials":"G.","Affiliation":"Toxicological Center, University of Antwerp","Discriminator":null,"CorporateFlag":0,"BEntID":277570,"AutID":179163,"OrderNr":2,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":"Universiteit Antwerpen; Faculteit Farmaceutische, Biomedische en Diergeneeskundige Wetenschappen; Toxicologisch Centrum","ORCID":"0000-0002-2212-8617","PersID":30246,"InsID":111},{"AutName":"Voorspoels","Firstname":"Stefan","Initials":"S.","Affiliation":"Flemish Institute for Technological Research (Vito NV)","Discriminator":null,"CorporateFlag":0,"BEntID":277570,"AutID":256854,"OrderNr":3,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"VITO","InsFSN":"Vlaamse overheid; Beleidsdomein Economie, Wetenschap en Innovatie; Vlaamse Instelling voor Technologisch Onderzoek","ORCID":"0000-0002-9005-1930","PersID":3377,"InsID":138},{"AutName":"Symons","Firstname":"Nils","Initials":"N.","Affiliation":"Toxicological Center, University of Antwerp","Discriminator":null,"CorporateFlag":0,"BEntID":277570,"AutID":256855,"OrderNr":4,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":"Universiteit Antwerpen; Faculteit Farmaceutische, Biomedische en Diergeneeskundige Wetenschappen; Toxicologisch Centrum","ORCID":null,"PersID":35949,"InsID":111},{"AutName":"Malysheva","Firstname":"Svetlana","Initials":"S.V.","Affiliation":"Food, Medicines and Consumer Safety, The Scientific Institute of Public Health","Discriminator":null,"CorporateFlag":0,"BEntID":277570,"AutID":256856,"OrderNr":5,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"IPH","InsFSN":"Wetenschappelijk Instituut Volksgezondheid","ORCID":null,"PersID":35915,"InsID":4617},{"AutName":"Van Loco","Firstname":"Joris","Initials":"J.","Affiliation":"Food, Medicines and Consumer Safety, The Scientific Institute of Public Health","Discriminator":null,"CorporateFlag":0,"BEntID":277570,"AutID":257988,"OrderNr":6,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"IPH","InsFSN":"Wetenschappelijk Instituut Volksgezondheid","ORCID":"0000-0001-8439-3371","PersID":14348,"InsID":4617},{"AutName":"Covaci","Firstname":"Adrian","Initials":"A.","Affiliation":"Toxicological Center, University of Antwerp","Discriminator":null,"CorporateFlag":0,"BEntID":277570,"AutID":142927,"OrderNr":7,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":"Universiteit Antwerpen; Faculteit Farmaceutische, Biomedische en Diergeneeskundige Wetenschappen; Toxicologisch Centrum","ORCID":"0000-0003-0527-1136","PersID":2633,"InsID":111}],"mapdetails":null,"datasets":null,"monographs":null,"monparts":null,"serparts":null,"BEntOpen":null,"BEntPrivate":null,"availability":[{"BInstID":377418,"LibID":36,"BRefID":285545,"EmbargoDate":null,"FullEmbargoDate":null,"PhysMedID":16,"hasOCRd":null,"ShelfLocCode":"377418","RFID":null,"PaidValue":null,"Medium":"Server","Description":"Interne VLIZ documenten","Acronym":"VLIZ","Library":"Vlaams Instituut voor de Zee","DutchTerm":"Non-open access","URL":null,"ClassifID":228,"Classification":"Non-open access","ReqLink":1,"ClassifTypID":3,"URLLocation":"https://www.vliz.be/imisdocs/publications/","SubDir":1,"InternalReq":1,"LoggedInReq":1,"Disclaimer":"Disclaimer_VLIZ_Intern","DutchDisclaimer":"
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