{"refrec":{"BRefID":296171,"RR":"<b>Van Meel, K.; Fontas, C.; Van Grieken, R.; Queralt, I.; Hidalgo, M.; Margui, E.</b> (2008). Application of high-energy polarised beam energy dispersive X-ray fluorescence spectrometry to cadmium determination in saline solutions. <i>J. Anal. At. Spectrom. 23(7)</i>: 1034-1037. <a href=\"https://dx.doi.org/10.1039/b718382h\" target=\"_blank\">https://dx.doi.org/10.1039/b718382h</a>","BEntID":288260,"PublicFlag":1,"CheckedFlag":1,"wosflag":1,"vabbflag":1,"RefStringPartII":". <i>J. Anal. At. Spectrom. 23(7)</i>: 1034-1037. <a href=\"https://dx.doi.org/10.1039/b718382h\" target=\"_blank\">https://dx.doi.org/10.1039/b718382h</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":0,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Van Meel, K.; Fontas, C.; Van Grieken, R.; Queralt, I.; Hidalgo, M.; Margui, E.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Van Meel, K. <i>et al.</i>","Englishabstract":"In the present work, the analytical performance of a methodology based on a preconcentration using activated thin layers followed by high-energy polarised beam energy-dispersive <annref idrefs=\"ann1\">XRF spectrometry</annref> (HE-P-EDXRF) for the determination of trace amounts of Cd in saline solutions is presented. Linear calibration curves were obtained over the range 5–8000 μg L<small><sup>−1</sup></small> of Cd. When comparing the developed method to the direct analysis of Cd in sea <compname idrefs=\"chem1\">water</compname>, the detection limits were improved by several orders of magnitude, with values of 2.25 μg L<small><sup>−1</sup></small> (Al<small><sub>2</sub></small>O<small><sub>3</sub></small> target) and 0.075 μg L<small><sup>−1</sup></small> (CsI target), respectively. The accuracy was checked by analyzing spiked natural sea <compname idrefs=\"chem1\">water</compname> at Cd concentrations of 20, 100 and 600 μg L<small><sup>−1</sup></small> and results were compared to those obtained with anodic stripping voltametry and no significant differences at the 95% confidence level were found. The method has a good reproducibility over the investigated period of time and the precision of the method was better than 10%.","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Application of high-energy polarised beam energy dispersive X-ray fluorescence spectrometry to cadmium determination in saline solutions","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2026-04-18 01:32:04.473224","timezone_type":1,"timezone":"+02:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":null,"OtherDescriptors":null,"Notes":null,"AnaPub":2008,"MonPub":null,"DateUpdate":"2022-07-12","DateCreate":"2018-05-15","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000257146000017","VABBcode":null,"OpenAcc":0,"DOI":"10.1039/b718382h"},"refs":null,"anarec":{"AnaID":296171,"PubliDate":2008,"Pagination":"1034-1037","XtraPublOfAnaID":null,"ISBN":null,"Volume":"23","Issue":"7","BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":45606,"SerRR":"Journal of Analytical Atomic Spectrometry. 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