Document of bibliographic reference 301544

BibliographicReference record

Type
Bibliographic resource
Type of document
Journal article
BibLvlCode
AS
Title
Novel analgesic ω-conotoxins from the vermivorous cone snail Conus moncuri provide new insights into the evolution of conopeptides
Abstract
Cone snails are a diverse group of predatory marine invertebrates that deploy remarkably complex venoms to rapidly paralyse worm, mollusc or fish prey. ω-Conotoxins are neurotoxic peptides from cone snail venoms that inhibit Cav2.2 voltage-gated calcium channel, demonstrating potential for pain management via intrathecal (IT) administration. Here, we isolated and characterized two novel ω-conotoxins, MoVIA and MoVIB from Conus moncuri, the first to be identified in vermivorous (worm-hunting) cone snails. MoVIA and MoVIB potently inhibited human Cav2.2 in fluorimetric assays and rat Cav2.2 in patch clamp studies, and both potently displaced radiolabeled ω-conotoxin GVIA (125I-GVIA) from human SH-SY5Y cells and fish brain membranes (IC50 2–9 pM). Intriguingly, an arginine at position 13 in MoVIA and MoVIB replaced the functionally critical tyrosine found in piscivorous ω-conotoxins. To investigate its role, we synthesized MoVIB-[R13Y] and MVIIA-[Y13R]. Interestingly, MVIIA-[Y13R] completely lost Cav2.2 activity and MoVIB-[R13Y] had reduced activity, indicating that Arg at position 13 was preferred in these vermivorous ω-conotoxins whereas tyrosine 13 is preferred in piscivorous ω-conotoxins. MoVIB reversed pain behavior in a rat neuropathic pain model, confirming that vermivorous cone snails are a new source of analgesic ω-conotoxins. Given vermivorous cone snails are ancestral to piscivorous species, our findings support the repurposing of defensive venom peptides in the evolution of piscivorous Conidae.
WebOfScience code
https://www.webofscience.com/wos/woscc/full-record/WOS:000444022800001
Bibliographic citation
Sousa, S.R.; McArthur, J.R.; Brust, A.; Bhola, R.F.; Rosengren, K.J.; Ragnarsson, L.; Dutertre, S.; Alewood, P.F.; Christie, M.J.; Adams, D.J.; Vetter, I.; Lewis, R.J. (2018). Novel analgesic ω-conotoxins from the vermivorous cone snail Conus moncuri provide new insights into the evolution of conopeptides. NPG Scientific Reports 8(1): 15 pp. https://dx.doi.org/10.1038/s41598-018-31245-4
Is peer reviewed
true
Access rights
open access
Is accessible for free
true

Authors

author
Name
Silmara Sousa
author
Name
Jeffrey McArthur
author
Name
Andreas Brust
author
Name
Rebecca Bhola
author
Name
K. Johan Rosengren
author
Name
Lotten Ragnarsson
author
Name
Sébastien Dutertre
author
Name
Paul Alewood
author
Name
MacDonald Christie
author
Name
David Adams
author
Name
Irina Vetter
Identifier
https://orcid.org/0000-0002-3594-9588
author
Name
Richard Lewis

Links

referenced creativework
type
DOI
accessURL
https://dx.doi.org/10.1038/s41598-018-31245-4

Document metadata

date created
2018-09-25
date modified
2018-09-25