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Extreme biomimetics: Preservation of molecular detail in centimeter-scale samples of biological meshes laid down by sponges. <i>Science Advances 5(10)</i>: eaax2805. <a href=\"https://dx.doi.org/10.1126/sciadv.aax2805\" target=\"_blank\">https://dx.doi.org/10.1126/sciadv.aax2805</a>","BEntID":310751,"PublicFlag":1,"CheckedFlag":0,"wosflag":1,"vabbflag":0,"RefStringPartII":". <i>Science Advances 5(10)</i>: eaax2805. <a href=\"https://dx.doi.org/10.1126/sciadv.aax2805\" target=\"_blank\">https://dx.doi.org/10.1126/sciadv.aax2805</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":0,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Petrenko, I.; Summers, A.P.; Simon, P.; Zóltowska-Aksamitowska, S.; Motylenko, M.; Schimpf, C.; Rafaja, D.; Roth, F.; Kummer, K.; Brendler, E.; Pokrovsky, O.S.; Galli, R.; Wysokowski, M.; Meissner, H.; Niederschlag, E.; Joseph, Y.; Molodtsov, S.; Ereskovsky, A.V.; Sivkov, V.; Nekipelov, S.; Petrova, O.; Volkova, O.; Bertau, M.; Kraft, M.; Rogalev, A.; Kopani, M.; Jesioniowski, T.; Ehrlich, H.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Petrenko, I. <i>et al.</i>","Englishabstract":"Fabrication of biomimetic materials and scaffolds is usually a micro- or even nanoscale process; however, most testing and all manufacturing require larger-scale synthesis of nanoscale features. Here, we propose the utilization of naturally prefabricated three-dimensional (3D) spongin scaffolds that preserve molecular detail across centimeter-scale samples. The fine-scale structure of this collagenous resource is stable at temperatures of up to 1200°C and can produce up to 4 × 10–cm–large 3D microfibrous and nanoporous turbostratic graphite. Our findings highlight the fact that this turbostratic graphite is exceptional at preserving the nanostructural features typical for triple-helix collagen. The resulting carbon sponge resembles the shape and unique microarchitecture of the original spongin scaffold. Copper electroplating of the obtained composite leads to a hybrid material with excellent catalytic performance with respect to the reduction of p-nitrophenol in both freshwater and marine environments.","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Extreme biomimetics: Preservation of molecular detail in centimeter-scale samples of biological meshes laid down by sponges","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2024-12-10 01:33:17.368041","timezone_type":1,"timezone":"+01:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":null,"OtherDescriptors":null,"Notes":null,"AnaPub":2019,"MonPub":null,"DateUpdate":"2019-10-16","DateCreate":"2019-10-16","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000491132700007","VABBcode":null,"OpenAcc":1,"DOI":"10.1126/sciadv.aax2805"},"refs":null,"anarec":{"AnaID":317318,"PubliDate":2019,"Pagination":"eaax2805","XtraPublOfAnaID":null,"ISBN":null,"Volume":"5","Issue":"10","BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":248966,"SerRR":"Science Advances. 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