{"refrec":{"BRefID":323169,"RR":"<b>Yuan, D.; Delpierre, S.; Ke, K.; Raquez, J.-M.; Dubois, P.; Manas-Zloczower, I.</b> (2019). Biomimetic water-responsive self-healing epoxy with tunable properties. <i>ACS Applied Materials & Interfaces 11(19)</i>: 17853-17862. <a href=\"https://dx.doi.org/10.1021/acsami.9b04249\" target=\"_blank\">https://dx.doi.org/10.1021/acsami.9b04249</a>","BEntID":316640,"PublicFlag":1,"CheckedFlag":1,"wosflag":1,"vabbflag":1,"RefStringPartII":". <i>ACS Applied Materials & Interfaces 11(19)</i>: 17853-17862. <a href=\"https://dx.doi.org/10.1021/acsami.9b04249\" target=\"_blank\">https://dx.doi.org/10.1021/acsami.9b04249</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":0,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Yuan, D.; Delpierre, S.; Ke, K.; Raquez, J.-M.; Dubois, P.; Manas-Zloczower, I.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Yuan, D. <i>et al.</i>","Englishabstract":"As dynamic cross-linking networks are intrinsically weaker than permanent covalent networks, it is a big challenge to obtain a stiff self-healing polymer using reversible networks. Inspired by the self-healable and mechanically adaptive nature of sea cucumber, we design a water-responsive self-healing polymer system with reversible and permanent covalent networks by cross-linking poly(propylene glycol) with boroxine and epoxy. This double cross-linked structure is self-healing due to the boroxine reversible network as well as showing a room-temperature tensile modulus of 1059 MPa and a tensile stress of 37 MPa, on a par with classic thermosets. The dynamic boroxine bonds provide the self-healing response and enable up to 80% recovery in modulus and tensile strength upon water contact. The system shows superior adhesion to metal substrates by comparison with the commercial epoxy-based structural adhesive. Besides, this system can change modulus from a stiff thermoset to soft rubber (by a factor of 150) upon water stimulus, enabling potential applications of either direct or transform printing for micro/nanofabrication. Moreover, by incorporating conductive nanofillers, it becomes feasible to fabricate self-healing and versatile strain/stress sensors based on a single thermoset, with potential applications in wearable electronics for human healthcare.","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Biomimetic water-responsive self-healing epoxy with tunable properties","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2024-12-10 01:33:17.368041","timezone_type":1,"timezone":"+01:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":"self-healing; water-responsive; epoxy; boroxine; strain sensors","OtherDescriptors":null,"Notes":null,"AnaPub":2019,"MonPub":null,"DateUpdate":"2020-04-15","DateCreate":"2020-04-07","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000468364500081","VABBcode":null,"OpenAcc":0,"DOI":"10.1021/acsami.9b04249"},"refs":null,"anarec":{"AnaID":323169,"PubliDate":2019,"Pagination":"17853-17862","XtraPublOfAnaID":null,"ISBN":null,"Volume":"11","Issue":"19","BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":262381,"SerRR":"ACS Applied Materials & Interfaces. 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