{"refrec":{"BRefID":323231,"RR":"<b>Zhao, Y.; Li, Y.; Yuan, S.; Zhu, J.; Houtmeyers, S.; Li, J.; Dewil, R.; Gao, C.; Van der Bruggen, B.</b> (2019). A chemically assembled anion exchange membrane surface for monovalent anion selectivity and fouling reduction. <i>Journal of Materials Chemistry A 7(11)</i>: 6348-6356. <a href=\"https://dx.doi.org/10.1039/c8ta11868j\" target=\"_blank\">https://dx.doi.org/10.1039/c8ta11868j</a>","BEntID":316703,"PublicFlag":1,"CheckedFlag":1,"wosflag":1,"vabbflag":1,"RefStringPartII":". <i>Journal of Materials Chemistry A 7(11)</i>: 6348-6356. <a href=\"https://dx.doi.org/10.1039/c8ta11868j\" target=\"_blank\">https://dx.doi.org/10.1039/c8ta11868j</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":0,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Zhao, Y.; Li, Y.; Yuan, S.; Zhu, J.; Houtmeyers, S.; Li, J.; Dewil, R.; Gao, C.; Van der Bruggen, B.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Zhao, Y. <i>et al.</i>","Englishabstract":"Separation and extraction of monovalent anions from salt lakes or oceans is very important in view of a sustainable supply of industrial chemical compounds. In this work, a novel anion exchange membrane (AEM) with simultaneously enhanced monovalent anion selectivity and reduced organic fouling properties was synthesized through oxidative self-polymerization and an amide condensation reaction. Using a rapid deposition and polymerization procedure, <small>L</small>-dopa was coated on a commercial AEM surface to form an <small>L</small>-dopa polymer layer (<small>L</small>-PDA) by using CuSO<small><sub>4</sub></small> and H<small><sub>2</sub></small>O<small><sub>2</sub></small> as a trigger. This layer was chemically assembled with a 4-amino-benzenesulfonic acid monosodium salt (ABS) <em>via</em> an amide condensation reaction. The resulting anion exchange membrane <small>L</small>-PDA#ABS, with a unique hydrophilic characteristic and negatively charged thin layer, was found to have a high monovalent anion permselectivity of 5.29 (SO<small><sub>4</sub></small><small><sup>2−</sup></small>/Br<small><sup>−</sup></small>) and 4.66 (SO<small><sub>4</sub></small><small><sup>2−</sup></small>/Cl<small><sup>−</sup></small>) in electrodialysis (ED) (10 min, initial concentration of 50 mM Br<small><sup>−</sup></small>, Cl<small><sup>−</sup></small> and SO<small><sub>4</sub></small><small><sup>2−</sup></small>, and current density of 10.00 mA cm<small><sup>−2</sup></small>), while the original AEM had corresponding permselectivities of 1.22 and 1.00. Furthermore, the selective separation efficiency parameter of the <small>L</small>-PDA#ABS AEM in SO<small><sub>4</sub></small><small><sup>2−</sup></small>/Br<small><sup>−</sup></small> and SO<small><sub>4</sub></small><small><sup>2−</sup></small>/Cl<small><sup>−</sup></small> was 66% and 63%, which is higher than those of the original AEM (8% and 2%). Sodium dodecyl benzene sulfonate, bovine serum albumin and humic acid were used as model organic fouling materials; the <small>L</small>-PDA#ABS AEM has a much higher antifouling potential than a commercial reference AEM. The work also demonstrated that the chemically assembled functional layer with high stability was suitable for long term application.","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"A chemically assembled anion exchange membrane surface for monovalent anion selectivity and fouling reduction","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2024-12-10 01:33:01.897972","timezone_type":1,"timezone":"+01:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":null,"OtherDescriptors":null,"Notes":null,"AnaPub":2019,"MonPub":null,"DateUpdate":"2020-04-16","DateCreate":"2020-04-07","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000463970400045","VABBcode":null,"OpenAcc":0,"DOI":"10.1039/c8ta11868j"},"refs":null,"anarec":{"AnaID":323231,"PubliDate":2019,"Pagination":"6348-6356","XtraPublOfAnaID":null,"ISBN":null,"Volume":"7","Issue":"11","BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":272501,"SerRR":"Journal of Materials Chemistry A. 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