{"refrec":{"BRefID":350305,"RR":"<b>Freeman, D.H.; Ward, C.P.</b> (2022). Sunlight-driven dissolution is a major fate of oil at sea. <i>Science Advances 8(7)</i>: eabl7605. <a href=\"https://dx.doi.org/10.1126/sciadv.abl7605\" target=\"_blank\">https://dx.doi.org/10.1126/sciadv.abl7605</a>","BEntID":348001,"PublicFlag":1,"CheckedFlag":0,"wosflag":1,"vabbflag":0,"RefStringPartII":". <i>Science Advances 8(7)</i>: eabl7605. <a href=\"https://dx.doi.org/10.1126/sciadv.abl7605\" target=\"_blank\">https://dx.doi.org/10.1126/sciadv.abl7605</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":1,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Freeman, D.H.; Ward, C.P.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Freeman, D.H.; Ward, C.P.","Englishabstract":"Oxygenation reactions initiated by sunlight can transform insoluble components of crude oil at sea into water-soluble products, a process called photo-dissolution. First reported a half century ago, photo-dissolution has never been included in spill models because key parameters required for rate modeling were unknown, including the wavelength and photon dose dependence. Here, we experimentally quantified photo-dissolution as a function of wavelength and photon dose, making possible a sensitivity analysis of environmental variables in hypothetical spill scenarios and a mass balance assessment for the 2010 Deepwater Horizon (DwH) spill. The sensitivity analysis revealed that rates were most sensitive to oil slick thickness, season/latitude, and wavelength and less sensitive to photon dose. We estimate that 3 to 17% (best estimate 8%) of DwH surface oil was subject to photo-dissolution, comparable in magnitude to other widely recognized fate processes. Our findings invite a critical reevaluation of surface oil budgets for both DwH and future spills at sea.","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Sunlight-driven dissolution is a major fate of oil at sea","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2024-12-10 01:33:17.368041","timezone_type":1,"timezone":"+01:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":null,"OtherDescriptors":null,"Notes":null,"AnaPub":2022,"MonPub":null,"DateUpdate":"2022-03-10","DateCreate":"2022-03-10","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000757399100021","VABBcode":null,"OpenAcc":1,"DOI":"10.1126/sciadv.abl7605"},"refs":null,"anarec":{"AnaID":350305,"PubliDate":2022,"Pagination":"eabl7605","XtraPublOfAnaID":null,"ISBN":null,"Volume":"8","Issue":"7","BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":248966,"SerRR":"Science Advances. 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