{"refrec":{"BRefID":35226,"RR":"<b>Elghalbzouri, F.; Wollast, R.</b> (2002). Influence of diagenetic processes on the distribution and accumulation of major and trace elements in the sediments of the Scheldt estuary, <b><i>in</i></b>: <i>ECSA Local Meeting: ecological structures and functions in the Scheldt Estuary: from past to future, Antwerp, Belgium October 7-10, 2002: abstract book.</i> pp. 72","BEntID":35226,"PublicFlag":1,"CheckedFlag":0,"wosflag":null,"vabbflag":null,"RefStringPartII":", <b><i>in</i></b>: <i>ECSA Local Meeting: ecological structures and functions in the Scheldt Estuary: from past to future, Antwerp, Belgium October 7-10, 2002: abstract book.</i> pp. 72","DocTypID":17,"DocType":"Book chapters","MarineFlag":1,"FreshFlag":0,"BrackishFlag":1,"TerrestrialFlag":0,"Authorstring":"Elghalbzouri, F.; Wollast, R.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Elghalbzouri, F.; Wollast, R.","Englishabstract":"Sediment cores were carefully collected with a box corer in three areas of the Scheldt estuary (Antwerpen, Doel, Terneuzen) in August and repeated in December. The 20 upper cm were sliced under a nitrogen atmosphere in 0.5-1 cm thick layers. The slices were then centrifuged in order to separate the interstitial water from the solid phase. The following elements were determined in the solid phase Si, Al, Fe, Ca, Mg, Mn, Co, Zn, Cd, Cu, Pb, Corg and Norg. In addition, the following parameters were also measured in the pore waters: salinity, alkalinity, DIC, pH, DOC, NO<sub>3</sub>, NH<sub>4</sub>, PO<sub>4</sub>, Si, Fe, Ca, Mg, Mn, Co, Zn, Cd, Cu and Pb. The results for one core taken as an example will be shown on the poster. The vertical distribution of most major and minor elements remains rather constant except that of organic carbon whose concentration profile is scattered, reflecting the presence of thin mud layers and lenses in sandy deposits. The vertical profile of dissolved elements in pore waters exhibit generally marked gradients linked to the bacterial degradation of organic matter imposing strongly reducing conditions below the water-sediment interface. This is demonstrated by the rapid decrease of nitrate, the release of manganese and iron and finally the consumption of sulfate. The concentrations of trace elements fluctuate markedly in relation to dissolution and precipitation reactions. In order to obtain additional information on the speciation of trace elements, titration experiments of the solid phase by HCl have been performed during which the release of major and minor elements are measured. The similarity in behaviour between elements allow to demonstrate their close association. This is for example the case of Mn and Co; Zn, Cd and S<sup>=</sup>; Cu and Al; Pb and Fe. The use of a diagenetic model proposed by Yifenga and Van Cappellen (1996 ) is presently tested and tentatively improved to include the description of the behaviour of trace elements. Preliminary results will be shown.","AbstractOtherLang":null,"BibLvlCode":"AM","StandardTitle":"Influence of diagenetic processes on the distribution and accumulation of major and trace elements in the sediments of the Scheldt estuary","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2025-07-02 08:33:14.980000","timezone_type":1,"timezone":"+00:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":null,"OtherDescriptors":"Scheldt estuary (Antwerpen, Doel, Terneuzen)","Notes":null,"AnaPub":2002,"MonPub":null,"DateUpdate":"2015-11-16","DateCreate":"2003-05-27","SecASFANote":null,"ConfID":null,"PeerRev":0,"VlizCoreFlag":1,"WoScode":null,"VABBcode":null,"OpenAcc":1},"refs":null,"anarec":{"AnaID":35226,"PubliDate":2002,"Pagination":"72","XtraPublOfAnaID":null,"ISBN":null,"Volume":null,"Issue":null,"BRefMon":35114,"BRefMonRR":"(2002). ECSA Local Meeting: Ecological structures and functions in the Scheldt Estuary: from past to future, Antwerp, Belgium October 7-10, 2002: abstract book. University of Antwerp: Antwerp. 73 + 1 cd-rom pp.","BRefXtra":null,"BRefXtraRR":null,"SerBRefID":null,"SerRR":null,"StandardTitleSer":null,"ISSN":null,"AbbrevSer":null,"StandardTitleMon":"ECSA Local Meeting: Ecological structures and functions in the Scheldt Estuary: from past to future, Antwerp, Belgium October 7-10, 2002: abstract book","StartPage":72,"Pages":72,"ToPubliDate":null,"BRefBibLvlCode":"M","SerNotes":null},"monrec":null,"serrec":null,"relations":null,"relationsRev":null,"addrec":null,"othpubs":null,"ownerships":null,"authors":[{"AutName":"Elghalbzouri","Firstname":null,"Initials":"F.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":35226,"AutID":37702,"OrderNr":1,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":3928,"InsID":null},{"AutName":"Wollast","Firstname":"Roland","Initials":"R.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":35226,"AutID":4594,"OrderNr":2,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":208,"InsID":null}],"mapdetails":null,"datasets":null,"monographs":null,"monparts":null,"serparts":null,"BEntOpen":null,"BEntPrivate":null,"availability":[{"BInstID":280646,"LibID":36,"BRefID":35226,"EmbargoDate":null,"FullEmbargoDate":null,"PhysMedID":16,"hasOCRd":1,"ShelfLocCode":"280646","RFID":null,"PaidValue":null,"Medium":"Server","Description":"VLIZ Open Access","Acronym":"VLIZ","Library":"Vlaams Instituut voor de Zee","DutchTerm":"Open access","URL":null,"ClassifID":53,"Classification":"Open access","ReqLink":null,"ClassifTypID":1,"URLLocation":"https://www.vliz.be/imisdocs/publications/","SubDir":null,"InternalReq":0,"LoggedInReq":0,"Disclaimer":null,"DutchDisclaimer":null,"FileFormat":".pdf","FileDescr":"pdf","InsPub":1,"InsID":36,"FileFormID":6,"LendableFlag":1,"PublicFlag":1,"orderLib":"A","Notes":null,"AccConID":null,"AccessConstraint":null,"LicURL":null}],"litstyles":[{"LitStyID":16,"Style":"Summary"}],"thespers":null,"arch2discl":null,"SERpubls":null,"MONpubls":[{"PublName":"University of Antwerp","Place":"Antwerp"}],"pictures":[],"thestermsPath":[{"ThesaurusTerm":"Belgium, Schelde R.","ThestID":183117,"Acronym":"ASFA_GEOT","ThesTermPath":"Belgium, Schelde R."},{"ThesaurusTerm":"Dissolved chemicals","ThestID":2375,"Acronym":"ASFA","ThesTermPath":"Dissolved chemicals"},{"ThesaurusTerm":"Vertical distribution","ThestID":8971,"Acronym":"ASFA","ThesTermPath":"Distribution > Geographical distribution > Vertical distribution"},{"ThesaurusTerm":"Models","ThestID":5270,"Acronym":"ASFA","ThesTermPath":"Models"},{"ThesaurusTerm":"Organic carbon","ThestID":5828,"Acronym":"ASFA","ThesTermPath":"Organic matter > Carbon > Organic carbon"},{"ThesaurusTerm":"Vertical profiles","ThestID":8976,"Acronym":"ASFA","ThesTermPath":"Profiles > Vertical profiles"},{"ThesaurusTerm":"Diagenesis","ThestID":2293,"Acronym":"ASFA","ThesTermPath":"Sedimentation > Diagenesis"},{"ThesaurusTerm":"Sediments","ThestID":7403,"Acronym":"ASFA","ThesTermPath":"Sediments"},{"ThesaurusTerm":"Trace elements","ThestID":8672,"Acronym":"ASFA","ThesTermPath":"Trace elements"}],"thestermsASFA":[{"ThesaurusTerm":"Belgium, Schelde R."},{"ThesaurusTerm":"Diagenesis"},{"ThesaurusTerm":"Dissolved chemicals"},{"ThesaurusTerm":"Models"},{"ThesaurusTerm":"Organic carbon"},{"ThesaurusTerm":"Sediments"},{"ThesaurusTerm":"Trace elements"},{"ThesaurusTerm":"Vertical distribution"},{"ThesaurusTerm":"Vertical profiles"}],"taxtermsASFA":null,"geotermsASFA":[{"GeoTerm":"Doel"},{"GeoTerm":"Schelde"},{"GeoTerm":"Terneuzen"}],"collections":[{"Collection":"OMA - Open Marien Archief","ShortName":"OMA"},{"Collection":"ScheldeMonitor","ShortName":"scheldemonitor"}],"conf":null,"proj":null,"Physdatasets":null,"spcols":{"222":{"SpName":"BMB - Belgische Mariene Bibliografie","SpColID":222,"ParSpColID":null,"TopParID":null,"ShortName":"BMB","URLLocation":null,"LibID":36,"OpenRepoFlag":null,"SpTypID":null,"TopParIDNotWebsite":null,"SpColPath":"BMB"},"867":{"SpName":"IMIS themes","SpColID":867,"ParSpColID":null,"TopParID":null,"ShortName":"IMIS themes","URLLocation":null,"LibID":null,"OpenRepoFlag":null,"SpTypID":null,"TopParIDNotWebsite":null,"SpColPath":"IMIS themes"},"221":{"SpName":"OMA - Open Marien Archief","SpColID":221,"ParSpColID":null,"TopParID":null,"ShortName":"OMA","URLLocation":null,"LibID":36,"OpenRepoFlag":1,"SpTypID":null,"TopParIDNotWebsite":null,"SpColPath":"OMA"},"639":{"SpName":"Physics and chemistry","SpColID":639,"ParSpColID":867,"TopParID":867,"ShortName":"Fysicochemie","URLLocation":null,"LibID":null,"OpenRepoFlag":null,"SpTypID":null,"TopParIDNotWebsite":867,"SpColPath":"IMIS themes/Fysicochemie"},"656":{"SpName":"Physics and chemistry: Pollution","SpColID":656,"ParSpColID":639,"TopParID":867,"ShortName":"Fysicochemie: Verontreiniging","URLLocation":null,"LibID":null,"OpenRepoFlag":null,"SpTypID":null,"TopParIDNotWebsite":867,"SpColPath":"IMIS themes/Fysicochemie/Fysicochemie: Verontreiniging"},"654":{"SpName":"Physics and chemistry: Quality of bottom sediments","SpColID":654,"ParSpColID":639,"TopParID":867,"ShortName":"Fysicochemie: Waterbodemkwaliteit","URLLocation":null,"LibID":null,"OpenRepoFlag":null,"SpTypID":null,"TopParIDNotWebsite":867,"SpColPath":"IMIS themes/Fysicochemie/Fysicochemie: Waterbodemkwaliteit"},"27":{"SpName":"ScheldeMonitor","SpColID":27,"ParSpColID":null,"TopParID":null,"ShortName":"scheldemonitor","URLLocation":null,"LibID":null,"OpenRepoFlag":null,"SpTypID":null,"TopParIDNotWebsite":null,"SpColPath":"scheldemonitor"}},"doi":null,"publs":null,"serparttypes":null,"monauthors":null,"MParts":null,"SParts":null,"hLibs":null,"langs":[{"BEntID":35226,"AbstractFlag":0,"LangID":15,"LangCode":"en","Lang":"English","DutchTerm":"Engels","LangCodeExtended":"eng"},{"BEntID":35226,"AbstractFlag":1,"LangID":15,"LangCode":"en","Lang":"English","DutchTerm":"Engels","LangCodeExtended":"eng"}],"urls":null,"thesterms":[{"ThesaurusTerm":"Belgium, Schelde R.","ThestID":183117,"Acronym":"ASFA_GEOT","ThesTypID":34,"ThesType":"ASFA Geoterms"},{"ThesaurusTerm":"Diagenesis","ThestID":2293,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Dissolved chemicals","ThestID":2375,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Models","ThestID":5270,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Organic carbon","ThestID":5828,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Sediments","ThestID":7403,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Trace elements","ThestID":8672,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Vertical distribution","ThestID":8971,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Vertical profiles","ThestID":8976,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"}],"taxterms":null,"geoterms":[{"GeoTerm":"Doel","GeoObjectID":9108,"GeotID":6287},{"GeoTerm":"Schelde","GeoObjectID":2542,"GeotID":1401},{"GeoTerm":"Terneuzen","GeoObjectID":213,"GeotID":6269}],"othterms":[{"OtherTerm":"Scheldt estuary (antwerpen)","OthtID":4262}],"asfacodes":null,"asfa2codes":null,"thestermsFRIS":[{"ThesaurusTerm":"Belgium, Schelde R.","DutchTerm":null,"ThestID":183117,"Acronym":"ASFA_GEOT","ThesTypID":34,"ThesType":"ASFA Geoterms"},{"ThesaurusTerm":"Diagenesis","DutchTerm":"Diagenese","ThestID":2293,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Dissolved chemicals","DutchTerm":"Opgeloste chemicaliën","ThestID":2375,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Models","DutchTerm":"Modellen","ThestID":5270,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Organic carbon","DutchTerm":"Organisch koolstof","ThestID":5828,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Sediments","DutchTerm":"Sedimenten","ThestID":7403,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Trace elements","DutchTerm":"Sporenelementen","ThestID":8672,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Vertical distribution","DutchTerm":"Verticale verdeling","ThestID":8971,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"},{"ThesaurusTerm":"Vertical profiles","DutchTerm":"Verticale profielen","ThestID":8976,"Acronym":"ASFA","ThesTypID":1,"ThesType":"ASFA Thesaurus List"}],"taxtermsFRIS":null,"geotermsFRIS":[{"GeoTerm":"Doel","DutchTerm":"Doel"},{"GeoTerm":"Schelde","DutchTerm":"Schelde R."},{"GeoTerm":"Terneuzen","DutchTerm":"Terneuzen"}],"othtermsFRIS":[{"OtherTerm":"Scheldt estuary (antwerpen)","DutchTerm":null,"OthtID":4262}],"resmessage":"","complete":1,"sessions":{"newSesName":"Chisala, Chilekwa, C.","newSesDate":{"date":"2003-05-27 09:10:40.140000","timezone_type":3,"timezone":"Europe/Brussels"},"updSesName":"Bouchti, Zohra, Z.","updSesDate":{"date":"2015-11-16 09:16:25.163000","timezone_type":3,"timezone":"Europe/Brussels"}}}