{"refrec":{"BRefID":352550,"RR":"<b>Takashima, H.; Kanaya, Y.; Kato, S.; Friedrich, M.M.; Van Roozendael, M.; Taketani, F.; Miyakawa, T.; Komazaki, Y.; Cuevas, C.A.; Saiz-Lopez, A.; Sekiya, T.</b> (2022). Full latitudinal marine atmospheric measurements of iodine monoxide. <i>Atmos. Chem. Phys. 22(6)</i>: 4005-4018. <a href=\"https://dx.doi.org/10.5194/acp-22-4005-2022\" target=\"_blank\">https://dx.doi.org/10.5194/acp-22-4005-2022</a>","BEntID":350258,"PublicFlag":1,"CheckedFlag":1,"wosflag":1,"vabbflag":1,"RefStringPartII":". <i>Atmos. Chem. Phys. 22(6)</i>: 4005-4018. <a href=\"https://dx.doi.org/10.5194/acp-22-4005-2022\" target=\"_blank\">https://dx.doi.org/10.5194/acp-22-4005-2022</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":1,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Takashima, H.; Kanaya, Y.; Kato, S.; Friedrich, M.M.; Van Roozendael, M.; Taketani, F.; Miyakawa, T.; Komazaki, Y.; Cuevas, C.A.; Saiz-Lopez, A.; Sekiya, T.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Takashima, H. <i>et al.</i>","Englishabstract":"Iodine compounds destroy ozone (O<span class=\"inline-formula\"><sub>3</sub></span>) in the global troposphere and form new aerosols, thereby affecting the global radiative balance. However, few reports have described the latitudinal distribution of atmospheric iodine compounds. This work reports iodine monoxide (IO) measurements taken over unprecedented sampling areas from the Arctic to the Southern Hemisphere and spanning sea surface temperatures (SSTs) of approximately 0 to 31.5 <span class=\"inline-formula\"><sup>∘</sup></span>C. The highest IO concentrations were observed over the Western Pacific warm pool (WPWP), where O<span class=\"inline-formula\"><sub>3</sub></span> minima were also measured. There, a negative correlation was found between O<span class=\"inline-formula\"><sub>3</sub></span> and IO mixing ratios at extremely low O<span class=\"inline-formula\"><sub>3</sub></span> concentrations. This correlation is not explained readily by the O<span class=\"inline-formula\"><sub>3</sub></span>-dependent oceanic fluxes of photolabile inorganic iodine compounds, which is the dominant source in recent global-scale chemistry transport models representing iodine chemistry. Actually, the correlation rather implies that O<span class=\"inline-formula\"><sub>3</sub></span>-independent pathways can be similarly important in the WPWP. The O<span class=\"inline-formula\"><sub>3</sub></span>-independent fluxes result in a 15 % greater O<span class=\"inline-formula\"><sub>3</sub></span> loss than that estimated for O<span class=\"inline-formula\"><sub>3</sub></span>-dependent processes alone. The daily O<span class=\"inline-formula\"><sub>3</sub></span> loss rate related to iodine over the WPWP is as high as approximately 2 ppbv (parts per billion by volume) despite low O<span class=\"inline-formula\"><sub>3</sub></span> concentrations of approximately 10 ppbv, with the loss being up to 100 % greater than that without iodine. This finding suggests that warming SST driven by climate change might affect the marine atmospheric chemical balance through iodine–ozone chemistry.","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Full latitudinal marine atmospheric measurements of iodine monoxide","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2026-04-24 01:33:11.802244","timezone_type":1,"timezone":"+02:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":null,"OtherDescriptors":null,"Notes":null,"AnaPub":2022,"MonPub":null,"DateUpdate":"2022-06-14","DateCreate":"2022-06-13","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000776153500001","VABBcode":null,"OpenAcc":1,"DOI":"10.5194/acp-22-4005-2022"},"refs":null,"anarec":{"AnaID":352550,"PubliDate":2022,"Pagination":"4005-4018","XtraPublOfAnaID":null,"ISBN":null,"Volume":"22","Issue":"6","BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":114747,"SerRR":"Atmospheric Chemistry and Physics. 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