{"refrec":{"BRefID":353294,"RR":"<b>Verbeke, R.; Davenport, D.M.; Stassin, T.; Eyley, S.; Dickmann, M.; Cruz, A.J.; Dara, P.; Ritt, C.L.; Bogaerts, C.; Egger, W.; Ameloot, R.; Meersschaut, J.; Thielemans, W.; Koeckelberghs, G.; Elimelech, M.; Vankelecom, I.F.J.</b> (2021). Chlorine-resistant epoxide-based membranes for sustainable water desalination. <i>Environmental Science & Technology Letters 8(9)</i>: 818-824. <a href=\"https://dx.doi.org/10.1021/acs.estlett.1c00515\" target=\"_blank\">https://dx.doi.org/10.1021/acs.estlett.1c00515</a>","BEntID":351003,"PublicFlag":1,"CheckedFlag":1,"wosflag":1,"vabbflag":0,"RefStringPartII":". <i>Environmental Science & Technology Letters 8(9)</i>: 818-824. <a href=\"https://dx.doi.org/10.1021/acs.estlett.1c00515\" target=\"_blank\">https://dx.doi.org/10.1021/acs.estlett.1c00515</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":0,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Verbeke, R.; Davenport, D.M.; Stassin, T.; Eyley, S.; Dickmann, M.; Cruz, A.J.; Dara, P.; Ritt, C.L.; Bogaerts, C.; Egger, W.; Ameloot, R.; Meersschaut, J.; Thielemans, W.; Koeckelberghs, G.; Elimelech, M.; Vankelecom, I.F.J.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Verbeke, R. <i>et al.</i>","Englishabstract":"The hypersensitivity of state-of-the-art polyamide-based membranes to chlorine is a major source of premature membrane failure and module replacement in water desalination plants. This problem can currently only be solved by implementing pre- and post-treatment processes involving additional chemical use and energy input, thus increasing environmental, capital, and operational costs. Herein, we report a chlorine-, acid-, and base-resistant desalination membrane comprising a cross-linked epoxide-based polymer-selective layer with permanent positive charges. These novel membranes exhibit high mono- and divalent salt rejection (81% NaCl, 87% CaCl<sub>2</sub>, 89% MgCl<sub>2</sub>) and a water permeance of ∼2 L m<sup>–2</sup> h<sup>–1</sup> bar<sup>–1</sup>, i.e., desalination performance comparable to that of commercially available nanofiltration membranes. Unlike conventional polyamide-based membranes, this new generation of epoxide-based membranes takes advantage of the intrinsic chemical stability of ether bonds while achieving the polymer and charge density needed for desalination. In doing so, the stability of these membranes opens new horizons for sustainable water purification and many other separations in harsh media in a variety of applications (e.g., solvent recovery, gas separations, redox flow batteries).","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Chlorine-resistant epoxide-based membranes for sustainable water desalination","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2024-12-10 01:33:17.368041","timezone_type":1,"timezone":"+01:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":null,"OtherDescriptors":null,"Notes":null,"AnaPub":2021,"MonPub":null,"DateUpdate":"2024-11-04","DateCreate":"2022-07-01","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000696567300015","VABBcode":null,"OpenAcc":0,"DOI":"10.1021/acs.estlett.1c00515"},"refs":null,"anarec":{"AnaID":353294,"PubliDate":2021,"Pagination":"818-824","XtraPublOfAnaID":null,"ISBN":null,"Volume":"8","Issue":"9","BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":267579,"SerRR":"Environmental Science & Technology Letters. AMER CHEMICAL SOC: Washington.  ISSN 2328-8930","StandardTitleSer":"Environmental Science & Technology Letters","ISSN":"2328-8930","AbbrevSer":null,"StandardTitleMon":null,"StartPage":818,"Pages":7,"ToPubliDate":null,"BRefBibLvlCode":"S","SerNotes":null},"monrec":null,"serrec":null,"relations":null,"relationsRev":null,"addrec":null,"othpubs":null,"ownerships":null,"authors":[{"AutName":"Verbeke","Firstname":"Rhea","Initials":"R.","Affiliation":"Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions (cMACS), KU Leuven","Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493343,"OrderNr":1,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"CMACS","InsFSN":"KU Leuven; Faculteit bio-ingenieurswetenschappen; Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions","ORCID":"0000-0002-7130-6918","PersID":43685,"InsID":15213},{"AutName":"Davenport","Firstname":"Douglas","Initials":"D.M.","Affiliation":"Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions (cMACS), KU Leuven","Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493345,"OrderNr":2,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"CMACS","InsFSN":"KU Leuven; Faculteit bio-ingenieurswetenschappen; Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions","ORCID":null,"PersID":43721,"InsID":15213},{"AutName":"Stassin","Firstname":"Timothée","Initials":"T.","Affiliation":"Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions (cMACS), KU Leuven","Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493347,"OrderNr":3,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"CMACS","InsFSN":"KU Leuven; Faculteit bio-ingenieurswetenschappen; Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions","ORCID":"0000-0002-1175-4057","PersID":43722,"InsID":15213},{"AutName":"Eyley","Firstname":"Samuel","Initials":"S.","Affiliation":"Sustainable Materials Lab, Department of Chemical Engineering, KU Leuven","Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493348,"OrderNr":4,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":"KU Leuven; Campus Kortrijk; Faculteit Wetenschappen en Technologie; Sustainable Materials Lab","ORCID":"0000-0002-1929-8455","PersID":41381,"InsID":14596},{"AutName":"Dickmann","Firstname":"Marcel","Initials":"M.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493349,"OrderNr":5,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null},{"AutName":"Cruz","Firstname":"Alexander","Initials":"A.J.","Affiliation":"Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions (cMACS), KU Leuven","Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493350,"OrderNr":6,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"CMACS","InsFSN":"KU Leuven; Faculteit bio-ingenieurswetenschappen; Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions","ORCID":"0000-0002-5123-1162","PersID":43723,"InsID":15213},{"AutName":"Dara","Firstname":"Praveen","Initials":"P.","Affiliation":"IMEC","Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493351,"OrderNr":7,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"IMEC","InsFSN":"Interuniversitair Micro-Elektronica Centrum","ORCID":"0000-0002-2334-3976","PersID":41382,"InsID":3609},{"AutName":"Ritt","Firstname":"Cody","Initials":"C.L.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493352,"OrderNr":8,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null},{"AutName":"Bogaerts","Firstname":"Caroline","Initials":"C.","Affiliation":"Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions (cMACS), KU Leuven","Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493353,"OrderNr":9,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"CMACS","InsFSN":"KU Leuven; Faculteit bio-ingenieurswetenschappen; Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions","ORCID":null,"PersID":43724,"InsID":15213},{"AutName":"Egger","Firstname":"Werner","Initials":"W.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493354,"OrderNr":10,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null},{"AutName":"Ameloot","Firstname":"Rob","Initials":"R.","Affiliation":"Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions (cMACS), KU Leuven","Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493355,"OrderNr":11,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"CMACS","InsFSN":"KU Leuven; Faculteit bio-ingenieurswetenschappen; Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions","ORCID":"0000-0003-3178-5480","PersID":43725,"InsID":15213},{"AutName":"Meersschaut","Firstname":"Johan","Initials":"J.","Affiliation":"IMEC","Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493356,"OrderNr":12,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"IMEC","InsFSN":"Interuniversitair Micro-Elektronica Centrum","ORCID":"0000-0003-2467-1784","PersID":41383,"InsID":3609},{"AutName":"Thielemans","Firstname":"Wim","Initials":"W.","Affiliation":"Sustainable Materials Lab, Department of Chemical Engineering, KU Leuven","Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493357,"OrderNr":13,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":"KU Leuven; Campus Kortrijk; Faculteit Wetenschappen en Technologie; Sustainable Materials Lab","ORCID":"0000-0003-4451-1964","PersID":37244,"InsID":14596},{"AutName":"Koeckelberghs","Firstname":"Guy","Initials":"G.","Affiliation":"Laboratory for Polymer Synthesis, Faculty of Chemistry, KU Leuven","Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493358,"OrderNr":14,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null},{"AutName":"Elimelech","Firstname":"Menachem","Initials":"M.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":403283,"OrderNr":15,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null},{"AutName":"Vankelecom","Firstname":"Ivo","Initials":"I.F.J.","Affiliation":"Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions (cMACS), KU Leuven","Discriminator":null,"CorporateFlag":0,"BEntID":351003,"AutID":493360,"OrderNr":16,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"MTG","InsFSN":"KU Leuven; Faculteit bio-ingenieurswetenschappen; Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions; Membrane Technology Group","ORCID":"0000-0002-0104-9493","PersID":34047,"InsID":15214}],"mapdetails":null,"datasets":null,"monographs":null,"monparts":null,"serparts":null,"BEntOpen":null,"BEntPrivate":null,"availability":[{"BInstID":378678,"LibID":36,"BRefID":353294,"EmbargoDate":null,"FullEmbargoDate":null,"PhysMedID":16,"hasOCRd":null,"ShelfLocCode":"378678","RFID":null,"PaidValue":null,"Medium":"Server","Description":"Interne VLIZ documenten","Acronym":"VLIZ","Library":"Vlaams Instituut voor de Zee","DutchTerm":"Non-open access","URL":null,"ClassifID":228,"Classification":"Non-open access","ReqLink":1,"ClassifTypID":3,"URLLocation":"https://www.vliz.be/imisdocs/publications/","SubDir":1,"InternalReq":1,"LoggedInReq":1,"Disclaimer":"Disclaimer_VLIZ_Intern","DutchDisclaimer":"<p>Deze publicatie is enkel beschikbaar voor persoonlijk gebruik binnen de Innovocean site <br />en mag op geen enkele manier verder worden verspreid.</p>","FileFormat":".pdf","FileDescr":"pdf","InsPub":1,"InsID":36,"FileFormID":6,"LendableFlag":1,"PublicFlag":1,"orderLib":"A","Notes":null,"AccConID":null,"AccessConstraint":null,"LicURL":null}],"litstyles":null,"thespers":null,"arch2discl":null,"SERpubls":[{"PublName":"AMER CHEMICAL SOC","City":"Washington"}],"MONpubls":null,"pictures":[],"thestermsPath":null,"thestermsASFA":null,"taxtermsASFA":null,"geotermsASFA":null,"collections":null,"conf":null,"proj":null,"Physdatasets":null,"spcols":{"222":{"SpName":"BMB - Belgische Mariene Bibliografie","SpColID":222,"ParSpColID":null,"TopParID":null,"ShortName":"BMB","URLLocation":null,"LibID":36,"OpenRepoFlag":null,"SpTypID":null,"TopParIDNotWebsite":null,"SpColPath":"BMB"}},"doi":null,"publs":null,"serparttypes":null,"monauthors":null,"MParts":null,"SParts":null,"hLibs":null,"langs":[{"BEntID":351003,"AbstractFlag":0,"LangID":15,"LangCode":"en","Lang":"English","DutchTerm":"Engels","LangCodeExtended":"eng"},{"BEntID":351003,"AbstractFlag":1,"LangID":15,"LangCode":"en","Lang":"English","DutchTerm":"Engels","LangCodeExtended":"eng"}],"urls":[{"URL":"https://dx.doi.org/10.1021/acs.estlett.1c00515","externalID":"10.1021/acs.estlett.1c00515","URLTypeCode":"DOI","URLID":104012,"URLTypID":13,"URLType":"DOI","URLPrefix":"http://dx.doi.org/"}],"thesterms":null,"taxterms":null,"geoterms":null,"othterms":null,"asfacodes":null,"asfa2codes":null,"thestermsFRIS":null,"taxtermsFRIS":null,"geotermsFRIS":null,"othtermsFRIS":null,"resmessage":"","complete":1,"sessions":{"newSesName":"Bouchti, Zohra, Z.","newSesDate":{"date":"2022-07-01 14:21:55.743000","timezone_type":3,"timezone":"Europe/Brussels"},"updSesName":"Verheyde, Fons, F.","updSesDate":{"date":"2024-11-04 08:14:12.993000","timezone_type":3,"timezone":"Europe/Brussels"}}}