{"refrec":{"BRefID":361141,"RR":"<b>Vollebregt, A.; van Helmond, N.A.G.M.; Pit, S.; Kraal, P.; Slomp, C.P.</b> (2023). Trace metals as a redox proxy in Arabian Sea sediments in and below the oxygen minimum zone. <i>Chem. Geol. 618</i>: 121300. <a href=\"https://dx.doi.org/10.1016/j.chemgeo.2022.121300\" target=\"_blank\">https://dx.doi.org/10.1016/j.chemgeo.2022.121300</a>","BEntID":358856,"PublicFlag":1,"CheckedFlag":0,"wosflag":1,"vabbflag":1,"RefStringPartII":". <i>Chem. Geol. 618</i>: 121300. <a href=\"https://dx.doi.org/10.1016/j.chemgeo.2022.121300\" target=\"_blank\">https://dx.doi.org/10.1016/j.chemgeo.2022.121300</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":0,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Vollebregt, A.; van Helmond, N.A.G.M.; Pit, S.; Kraal, P.; Slomp, C.P.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Vollebregt, A. <i>et al.</i>","Englishabstract":"<p>    Sedimentary trace metals are widely used to reconstruct past bottom water    redox conditions. The calibration of trace metals as a redox proxy for    oxygen minimum zones (OMZs) can still be improved. Here, we combine pore    water and solid phase Mo, U, Re and V profiles with Fe and Mn data for tensites along a bottom water oxygen (2 to 83 μmol L<sup>−1</sup> O    <sub>2</sub>) and water depth gradient (885 to 3010 m) in and below the    perennial OMZ in the northern Arabian Sea (Murray Ridge). Trends in    sedimentary Mo, U and Re contents generally follow ambient bottom water    redox conditions, with the highest enrichments in OMZ sediments, supporting    the validity of these trace metals as redox proxies. Vanadium and Fe are    exclusively enriched in the sediments of the most anoxic OMZ site and do    not capture further redox changes in and below the OMZ. We attribute the    absence of a redox trend in sedimentary Fe content to the mildly reducing    conditions in the sediments, with little FeS formation and benthic release    of Fe. Manganese, in contrast, is depleted in the OMZ sediments and    enriched in sediments below the OMZ, in accordance with loss from OMZ    sediments and transfer of Mn to deeper sites (“Mn shuttling”). Manganese    oxides are likely a key carrier of Mo and V to the sediments, especially    below the OMZ, while diffusion across the sediment-water interface supplies    U. Sedimentary Mo, U and V contents in the present-day Arabian Sea OMZ are    generally lower than observed in other perennial OMZs. This may be related    to a lower input of organic matter in this part of the Arabian Sea when    compared to other OMZs, and hence, less anaerobic degradation of organic    matter and less authigenic fixation of metals, even at the same bottom    water oxygen concentrations. Our results have implications for the    detection of OMZs in the geological record, implying that thresholds in    trace metal concentrations for perennial OMZs may be lower than previously    considered. Comparison of our Mo, U, Re and V data to trace metal records    from 15 to 200 ka for the same Arabian Sea region suggests that the OMZ was    periodically wider and more reducing in the past</p>","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Trace metals as a redox proxy in Arabian Sea sediments in and below the oxygen minimum zone","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2026-04-17 01:32:47.557492","timezone_type":1,"timezone":"+02:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":"Molybdenum; Uranium; Iron; Manganese; Redox transect; Murray Ridge","OtherDescriptors":null,"Notes":null,"AnaPub":2023,"MonPub":null,"DateUpdate":"2023-02-14","DateCreate":"2023-02-14","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:000925297400001","VABBcode":null,"OpenAcc":1,"DOI":"10.1016/j.chemgeo.2022.121300"},"refs":null,"anarec":{"AnaID":361141,"PubliDate":2023,"Pagination":"121300","XtraPublOfAnaID":null,"ISBN":null,"Volume":"618","Issue":null,"BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":42560,"SerRR":"Chemical Geology. Elsevier: New York; London; Amsterdam.  ISSN 0009-2541; e-ISSN 1872-6836","StandardTitleSer":"Chemical Geology","ISSN":"0009-2541","AbbrevSer":"Chem. 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