{"refrec":{"BRefID":365768,"RR":"<b>Zhu, K.; Achterberg, E.P.; Bates, N.R.; Gerringa, L.J.A.; Middag, R.; Hopwood, M.J.; Gledhill, M.</b> (2023). Influence of changes in pH and temperature on the distribution of apparent iron solubility in the oceans. <i>Global Biogeochem. Cycles 37(5)</i>. <a href=\"https://dx.doi.org/10.1029/2022gb007617\" target=\"_blank\">https://dx.doi.org/10.1029/2022gb007617</a>","BEntID":363490,"PublicFlag":1,"CheckedFlag":0,"wosflag":1,"vabbflag":1,"RefStringPartII":". <i>Global Biogeochem. Cycles 37(5)</i>. <a href=\"https://dx.doi.org/10.1029/2022gb007617\" target=\"_blank\">https://dx.doi.org/10.1029/2022gb007617</a>","DocTypID":8,"DocType":"Journal article","MarineFlag":0,"FreshFlag":0,"BrackishFlag":0,"TerrestrialFlag":0,"Authorstring":"Zhu, K.; Achterberg, E.P.; Bates, N.R.; Gerringa, L.J.A.; Middag, R.; Hopwood, M.J.; Gledhill, M.","OrigTitleTranslFlag":0,"Authorstringtrunc":"Zhu, K. <i>et al.</i>","Englishabstract":" An insufficient supply of the micronutrient iron (Fe) limits  phytoplankton    growth across large parts of the ocean. Ambient Fe speciation and    solubility are largely dependent on seawater physico-chemical properties. We    calculated the apparent Fe solubility (SFe(III)<sub>app</sub>) at    equilibrium  for ambient conditions, where SFe(III) <sub>app</sub> is    defined as the sum  of aqueous inorganic Fe(III) species and Fe(III) bound    to organic matter formed  at a free Fe <sup>3+</sup> concentration equal to    the solubility of Fe  hydroxide. We compared the SFe(III) <sub>app</sub> to    measured dissolved Fe  (dFe) in the Atlantic and Pacific Oceans. The    SFe(III) <sub>app</sub> was  overall ∼2–4-fold higher than observed dFe  at    depths less than 1,000 m, ∼2-fold higher  than the dFe between 1,000 and    4,000 m and ∼3-fold  higher than dFe below 4,000 m.  Within the range of    used parameters, our results showed that there was a  similar trend in the    vertical distributions of horizontally averaged SFe(III) <sub>app</sub> and    dFe. Our results suggest that vertical dFe distributions are underpinned by    changes in SFe(III)<sub>app</sub>, which are driven by relative changes in    ambient pH and temperature. Since both pH and temperature are essential    parameters controlling ambient Fe speciation, these should be accounted for    in  investigations of changing Fe dynamics, particularly in the context of    ocean  acidification and warming.","AbstractOtherLang":null,"BibLvlCode":"AS","StandardTitle":"Influence of changes in pH and temperature on the distribution of apparent iron solubility in the oceans","OrigTitleLangCode":"en","OrigTitleLangCodeExtended":"eng","OrigTitleLangID":15,"DateLastModified":{"date":"2026-04-21 01:33:19.709326","timezone_type":1,"timezone":"+02:00"},"UserAccessRight":null,"UserAccID":null,"AuthorKeywords":"iron speciation; iron biogeochemistry; organic matter; dissolved organic carbon; Atlantic Ocean; Pacific Ocean; ocean acidification","OtherDescriptors":null,"Notes":null,"AnaPub":2023,"MonPub":null,"DateUpdate":"2023-07-20","DateCreate":"2023-07-20","SecASFANote":null,"ConfID":null,"PeerRev":1,"VlizCoreFlag":1,"WoScode":"WOS:001000101700001","VABBcode":null,"OpenAcc":1,"DOI":"10.1029/2022gb007617"},"refs":null,"anarec":{"AnaID":365768,"PubliDate":2023,"Pagination":null,"XtraPublOfAnaID":null,"ISBN":null,"Volume":"37","Issue":"5","BRefMon":null,"BRefMonRR":null,"BRefXtra":null,"BRefXtraRR":null,"SerBRefID":45841,"SerRR":"Global Biogeochemical Cycles. American Geophysical Union: Washington, DC.  ISSN 0886-6236; e-ISSN 1944-9224","StandardTitleSer":"Global Biogeochemical Cycles","ISSN":"0886-6236","AbbrevSer":"Global Biogeochem. Cycles","StandardTitleMon":null,"StartPage":null,"Pages":null,"ToPubliDate":null,"BRefBibLvlCode":"S","SerNotes":null},"monrec":null,"serrec":null,"relations":null,"relationsRev":null,"addrec":null,"othpubs":null,"ownerships":null,"authors":[{"AutName":"Zhu","Firstname":"Kechen","Initials":"K.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":363490,"AutID":438381,"OrderNr":1,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null},{"AutName":"Achterberg","Firstname":"Eric","Initials":"E.P.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":363490,"AutID":148678,"OrderNr":2,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null},{"AutName":"Bates","Firstname":"Nicholas","Initials":"N.R.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":363490,"AutID":32791,"OrderNr":3,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null},{"AutName":"Gerringa","Firstname":"Loes","Initials":"L.J.A.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":363490,"AutID":212148,"OrderNr":4,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"OCS","InsFSN":"Koninklijk Nederlands Instituut voor Onderzoek der Zee; Ocean Sciences","ORCID":"0000-0002-3139-8352","PersID":27931,"InsID":13654},{"AutName":"Middag","Firstname":"Rob","Initials":"R.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":363490,"AutID":252610,"OrderNr":5,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":"OCS","InsFSN":"Koninklijk Nederlands Instituut voor Onderzoek der Zee; Ocean Sciences","ORCID":"0000-0002-3326-530X","PersID":29858,"InsID":13654},{"AutName":"Hopwood","Firstname":"Mark","Initials":"M.J.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":363490,"AutID":251440,"OrderNr":6,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null},{"AutName":"Gledhill","Firstname":"Martha","Initials":"M.","Affiliation":null,"Discriminator":null,"CorporateFlag":0,"BEntID":363490,"AutID":48277,"OrderNr":7,"DegrID":null,"EditorFlag":0,"CorrespFlag":0,"IllustratorFlag":0,"ReviserFlag":0,"TranslatorFlag":0,"InsAcronym":null,"InsFSN":null,"ORCID":null,"PersID":null,"InsID":null}],"mapdetails":null,"datasets":null,"monographs":null,"monparts":null,"serparts":null,"BEntOpen":363490,"BEntPrivate":null,"availability":[{"BInstID":391193,"LibID":2779,"BRefID":365768,"EmbargoDate":null,"FullEmbargoDate":null,"PhysMedID":16,"hasOCRd":1,"ShelfLocCode":"391193","RFID":null,"PaidValue":null,"Medium":"Server","Description":null,"Acronym":null,"Library":"NIOZ","DutchTerm":null,"URL":null,"ClassifID":260,"Classification":"NIOZ Open Repository","ReqLink":null,"ClassifTypID":1,"URLLocation":"https://www.vliz.be/imisdocs/publications/","SubDir":1,"InternalReq":null,"LoggedInReq":null,"Disclaimer":"Disclaimer_NIOZ","DutchDisclaimer":null,"FileFormat":".pdf","FileDescr":"pdf","InsPub":1,"InsID":397,"FileFormID":6,"LendableFlag":null,"PublicFlag":1,"orderLib":"NIOZ","Notes":null,"AccConID":24,"AccessConstraint":"Attribution-NonCommercial (CC BY-NC)","LicURL":"https://creativecommons.org/licenses/by-nc/4.0"}],"litstyles":null,"thespers":null,"arch2discl":805,"SERpubls":[{"PublName":"American Geophysical Union","City":"Washington, DC"}],"MONpubls":null,"pictures":[],"thestermsPath":null,"thestermsASFA":null,"taxtermsASFA":null,"geotermsASFA":null,"collections":null,"conf":null,"proj":null,"Physdatasets":null,"spcols":{"805":{"SpName":"Koninklijk Nederlands Instituut voor Onderzoek der Zee","SpColID":805,"ParSpColID":null,"TopParID":null,"ShortName":"NIOZ","URLLocation":"https://www.vliz.be/imis/nioz/imis.php?refid=","LibID":2779,"OpenRepoFlag":1,"SpTypID":1,"TopParIDNotWebsite":null,"SpColPath":"NIOZ"}},"doi":null,"publs":null,"serparttypes":null,"monauthors":null,"MParts":null,"SParts":null,"hLibs":null,"langs":[{"BEntID":363490,"AbstractFlag":0,"LangID":15,"LangCode":"en","Lang":"English","DutchTerm":"Engels","LangCodeExtended":"eng"},{"BEntID":363490,"AbstractFlag":1,"LangID":15,"LangCode":"en","Lang":"English","DutchTerm":"Engels","LangCodeExtended":"eng"}],"urls":[{"URL":"https://doi.pangaea.de/10.1594/PANGAEA.952541","externalID":"10.1594/PANGAEA.952541","URLTypeCode":null,"URLID":118068,"URLTypID":37,"URLType":"Additional info","URLPrefix":null},{"URL":"https://dx.doi.org/10.1029/2022gb007617","externalID":"10.1029/2022gb007617","URLTypeCode":"DOI","URLID":118067,"URLTypID":13,"URLType":"DOI","URLPrefix":"http://dx.doi.org/"}],"thesterms":null,"taxterms":null,"geoterms":null,"othterms":null,"asfacodes":null,"asfa2codes":null,"thestermsFRIS":null,"taxtermsFRIS":null,"geotermsFRIS":null,"othtermsFRIS":null,"resmessage":"","complete":1,"sessions":{"newSesName":"daan.van.loon@nioz.nl","newSesDate":{"date":"2023-07-20 10:19:06.600000","timezone_type":3,"timezone":"Europe/Brussels"},"updSesName":"daan.van.loon@nioz.nl","updSesDate":{"date":"2023-07-20 10:19:06.600000","timezone_type":3,"timezone":"Europe/Brussels"}}}