Synthesis of C@Ni-Al LDH HSS for efficient U-entrapment from seawater

Yuan, Y.; Yin, C.; Zhang, Y.; Chen, Z.; Xu, Y.; Wang, J.

doi:/10.1038/s41598-019-42252-4

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Synthesis of C@Ni-Al LDH HSS for efficient U-entrapment from seawater

Yuan, Y.; Yin, C.; Zhang, Y.; Chen, Z.; Xu, Y.; Wang, J. (2019). Synthesis of C@Ni-Al LDH HSS for efficient U-entrapment from seawater. NPG Scientific Reports 9(1): 13 pp. https://dx.doi.org/10.1038/s41598-019-42252-4

In: Scientific Reports (Nature Publishing Group). Nature Publishing Group: London. ISSN 2045-2322; e-ISSN 2045-2322, more

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Yuan, Y. Yin, C. Zhang, Y.	Chen, Z. Xu, Y. Wang, J.

Abstract

In this paper, a double hollow spherical shell composite modified with layered double hydroxide (C@Ni-Al LDH HSS) was fabricated for uranium(VI) (U(VI)) adsorption. Various batch experiments were carried out to investigate the influence of pH, concentration, time and coexistence ion on extraction. The results showed that the adsorption processes of U(VI) onto C@Ni-Al LDH HSS were spontaneous and endothermic and closely followed pseudo-second-order and Langmuir isotherm models. The equilibrium time and maximum adsorption capacity of C@Ni-Al LDH HSS was 360 min and 545.9 mg g−1. FT-IR and XPS analyses proved that the adsorption behavior was primarily attributed to the strong interaction between oxygen-containing functional groups and U(VI). Moreover, the extraction of trace U(VI) (μg L−1) in artificial and natural seawater was also studied. The results showed that C@Ni-Al LDH HSS provided a promising application for the efficient extraction of U(VI) from seawater.

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