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Chemical analysis of estrogens, organochlorine and organonitrogen pesticides as possible endocrine disruptors Scheldt-estuary [Chemische analyse van oestrogenen, organochloor en organostikstof pesticiden als mogelijke endocriene verstoorders in het Schelde-estuarium] Citation Noppe, H.; De Brabander, H.; De Wasch, K.; Laboratory for Chemical Analysis - Ugent, Belgium; (2006): Chemical analysis of estrogens, organochlorine and organonitrogen pesticides as possible endocrine disruptors Scheldt-estuary. https://marineinfo.org/id/dataset/19 Contact:
Vakgroep Veterinaire Volksgezondheid & Voedselveiligheid (UGent-VVV), more Availability: Unrestricted after moratorium period Data are initially restricted, but the access condition relaxes to academic or unrestricted once a specified period of time after an event (such as collection, publication, completion of QC procedures or project cessation) has elapsed Description Water, sediment, suspended matter and biota were sampled along the Western Scheldt from 2002 to 2006. All matrices were analysed for estrogens, organochlorine and organonitrogen pesticides using SPE, HPLC, GC-MS/MS and LC-MS/MS. more In order to evaluate the potential risk of endocrine disruptors, the occurrence of these compounds needs to be documented. Water, sediment, suspended matter and biota were sampled along the Western Scheldt from 2002 to 2006. All matrices were analysed for estrogens, organochlorine and organonitrogen pesticides using SPE, HPLC, GC-MS/MS and LC-MS/MS. The aim this part of the ENDIS-RISKS project is to give an overview of the occurrence and the concentration of the selected endocrine disruptors in the Scheldt estuary. Scope Themes: Coastal studies (e.g. shores, estuaries), Environmental quality/pollution Keywords: Ecotoxicology, Estrogens, Fungicides, Herbicides, Hormones, Insecticides, Pesticides, Steroids, Water quality, ANE, Scheldt Estuary, ANE, Netherlands, Westerschelde, Bath, ANE, Netherlands, Westerschelde, Hansweert, ANE, Netherlands, Westerschelde, Terneuzen, ANE, Netherlands, Westerschelde, Verdronken Land van Saeftinge, ANE, Netherlands, Westerschelde, Vlissingen, Belgium, Zeeschelde, Antwerp, Belgium, Zeeschelde, Doel, Crangon crangon (Linnaeus, 1758), Neomysis integer (Leach, 1814) Geographical coverage ANE, Scheldt Estuary [Marine Regions] ANE, Netherlands, Westerschelde, Bath Stations [Marine Regions] S12 Coordinates: Long: 4,225; Lat: 51,365 [WGS84] ANE, Netherlands, Westerschelde, Hansweert Stations [Marine Regions] S07 Coordinates: Long: 4; Lat: 51,4367 [WGS84] ANE, Netherlands, Westerschelde, Terneuzen Stations [Marine Regions] S04 Coordinates: Long: 3,825; Lat: 51,345 [WGS84] ANE, Netherlands, Westerschelde, Verdronken Land van Saeftinge Stations [Marine Regions] S09 Coordinates: Long: 4,0783; Lat: 51,37 [WGS84] ANE, Netherlands, Westerschelde, Vlissingen Stations [Marine Regions] S01 Coordinates: Long: 3,57; Lat: 51,4167 [WGS84] Belgium, Zeeschelde, Antwerp Stations [Marine Regions] S22 Coordinates: Long: 4,3917; Lat: 51,2188 [WGS84] Belgium, Zeeschelde, Doel Stations [Marine Regions] S15 Coordinates: Long: 4,2733; Lat: 51,3133 [WGS84] Temporal coverage 2002 - 2006 Unknown Parameters Alpha-Estradiol Methodology Atrazine Methodology Beta-Estradiol Methodology Chlordane Endosulfan Estrone Methodology Ethinylestradiol Methodology Kepone Toxaphene Vinclozolin Alpha-Estradiol: SPE GCMS/MS (1) Description protocol for the detection of organonitrogen pesticides (atrazine, simazine, terbutylazine) in water samples: After pH adjustment, the samples are filtered and extracted using SDB solid phase extraction cartridges. The extracts are analysed by GC-MS/MS (EI). The data processing is performed by Xcalibur 1.3. and MSOffice Excel. The identification of the organonitrogen pesticides is based on the relative retention time and a specific mass spectrum. Quantification is performe Alpha-Estradiol: GC-EI-MS-MS Description protocol for pesticides and estrogenes in biota, SPM and sediment: Extraction is performed using accelerated solvent extraction (ASE). After HPLC fractionation or clean-up using the SPE from water analysis samples are analysed bij GC-EI-MS-MS Alpha-Estradiol: GC-EI-MS-MS Description protocol for pesticides and estrogenes in biota, SPM and sediment: Extraction is performed using accelerated solvent extraction (ASE). After HPLC fractionation or clean-up using the SPE from water analysis samples are analysed bij GC-EI-MS-MS Alpha-Estradiol: GC-EI-MS-MS Description protocol for pesticides and estrogenes in biota, SPM and sediment: Extraction is performed using accelerated solvent extraction (ASE). After HPLC fractionation or clean-up using the SPE from water analysis samples are analysed bij GC-EI-MS-MS Atrazine: GC-EI-MS-MS Description protocol for pesticides and estrogenes in biota, SPM and sediment: Extraction is performed using accelerated solvent extraction (ASE). After HPLC fractionation or clean-up using the SPE from water analysis samples are analysed bij GC-EI-MS-MS Atrazine: GC-EI-MS-MS Description protocol for pesticides and estrogenes in biota, SPM and sediment: Extraction is performed using accelerated solvent extraction (ASE). After HPLC fractionation or clean-up using the SPE from water analysis samples are analysed bij GC-EI-MS-MS Atrazine: SPE GCMS/MS (1) Description protocol for the detection of organonitrogen pesticides (atrazine, simazine, terbutylazine) in water samples: After pH adjustment, the samples are filtered and extracted using SDB solid phase extraction cartridges. The extracts are analysed by GC-MS/MS (EI). The data processing is performed by Xcalibur 1.3. and MSOffice Excel. The identification of the organonitrogen pesticides is based on the relative retention time and a specific mass spectrum. Quantification is performe Atrazine: GC-EI-MS-MS Description protocol for pesticides and estrogenes in biota, SPM and sediment: Extraction is performed using accelerated solvent extraction (ASE). After HPLC fractionation or clean-up using the SPE from water analysis samples are analysed bij GC-EI-MS-MS Beta-Estradiol: SPE GCMS/MS (1) Description protocol for the detection of organonitrogen pesticides (atrazine, simazine, terbutylazine) in water samples: After pH adjustment, the samples are filtered and extracted using SDB solid phase extraction cartridges. The extracts are analysed by GC-MS/MS (EI). The data processing is performed by Xcalibur 1.3. and MSOffice Excel. The identification of the organonitrogen pesticides is based on the relative retention time and a specific mass spectrum. Quantification is performe Beta-Estradiol: GC-EI-MS-MS Description protocol for pesticides and estrogenes in biota, SPM and sediment: Extraction is performed using accelerated solvent extraction (ASE). After HPLC fractionation or clean-up using the SPE from water analysis samples are analysed bij GC-EI-MS-MS Beta-Estradiol: SPE GCMS/MS (1) Description protocol for the detection of organonitrogen pesticides (atrazine, simazine, terbutylazine) in water samples: After pH adjustment, the samples are filtered and extracted using SDB solid phase extraction cartridges. The extracts are analysed by GC-MS/MS (EI). The data processing is performed by Xcalibur 1.3. and MSOffice Excel. The identification of the organonitrogen pesticides is based on the relative retention time and a specific mass spectrum. Quantification is performe Beta-Estradiol: GC-EI-MS-MS Description protocol for pesticides and estrogenes in biota, SPM and sediment: Extraction is performed using accelerated solvent extraction (ASE). After HPLC fractionation or clean-up using the SPE from water analysis samples are analysed bij GC-EI-MS-MS Estrone: GC-EI-MS-MS Description protocol for pesticides and estrogenes in biota, SPM and sediment: Extraction is performed using accelerated solvent extraction (ASE). After HPLC fractionation or clean-up using the SPE from water analysis samples are analysed bij GC-EI-MS-MS Estrone: GC-EI-MS-MS Description protocol for pesticides and estrogenes in biota, SPM and sediment: Extraction is performed using accelerated solvent extraction (ASE). After HPLC fractionation or clean-up using the SPE from water analysis samples are analysed bij GC-EI-MS-MS Estrone: SPE GCMS/MS (1) Description protocol for the detection of organonitrogen pesticides (atrazine, simazine, terbutylazine) in water samples: After pH adjustment, the samples are filtered and extracted using SDB solid phase extraction cartridges. The extracts are analysed by GC-MS/MS (EI). The data processing is performed by Xcalibur 1.3. and MSOffice Excel. The identification of the organonitrogen pesticides is based on the relative retention time and a specific mass spectrum. Quantification is performe Estrone: GC-EI-MS-MS Description protocol for pesticides and estrogenes in biota, SPM and sediment: Extraction is performed using accelerated solvent extraction (ASE). After HPLC fractionation or clean-up using the SPE from water analysis samples are analysed bij GC-EI-MS-MS Ethinylestradiol: GC-EI-MS-MS Description protocol for pesticides and estrogenes in biota, SPM and sediment: Extraction is performed using accelerated solvent extraction (ASE). After HPLC fractionation or clean-up using the SPE from water analysis samples are analysed bij GC-EI-MS-MS Ethinylestradiol: SPE GCMS/MS (1) Description protocol for the detection of organonitrogen pesticides (atrazine, simazine, terbutylazine) in water samples: After pH adjustment, the samples are filtered and extracted using SDB solid phase extraction cartridges. The extracts are analysed by GC-MS/MS (EI). The data processing is performed by Xcalibur 1.3. and MSOffice Excel. The identification of the organonitrogen pesticides is based on the relative retention time and a specific mass spectrum. Quantification is performe Ethinylestradiol: SPE GCMS/MS (1) Description protocol for the detection of organonitrogen pesticides (atrazine, simazine, terbutylazine) in water samples: After pH adjustment, the samples are filtered and extracted using SDB solid phase extraction cartridges. The extracts are analysed by GC-MS/MS (EI). The data processing is performed by Xcalibur 1.3. and MSOffice Excel. The identification of the organonitrogen pesticides is based on the relative retention time and a specific mass spectrum. Quantification is performe Ethinylestradiol: GC-EI-MS-MS Description protocol for pesticides and estrogenes in biota, SPM and sediment: Extraction is performed using accelerated solvent extraction (ASE). After HPLC fractionation or clean-up using the SPE from water analysis samples are analysed bij GC-EI-MS-MS Contributors Universiteit Gent; Faculteit Diergeneeskunde; Vakgroep Veterinaire Volksgezondheid & Voedselveiligheid; Laboratorium voor Chemische Analyse (LCA), more, data creator, data owner Belgian Science Policy (BELSPO), more, data owner Universiteit Gent; Faculteit Diergeneeskunde; Vakgroep Veterinaire Volksgezondheid & Voedselveiligheid (VVV), more Related datasets Parent dataset: ENDIS-RISKS fysico-chemical measurements and hyperbenthos in the Scheldt river, 2002-2006., more Project ENDIS-RISKS: Endocrine disruption in the Scheldt Estuary: distribution, exposure and effects, more Publication Based on this dataset Noppe, H. (2007). Occurrence of hormones in the Scheldt estuary: an analytical challenge!, in: Mees, J. et al. (Ed.) (2007). VLIZ Young Scientists' Day, Brugge, Belgium 2 March 2007: book of abstracts. VLIZ Special Publication, 39: pp. 14, more Noppe, H. et al. (2007). Multi-analyte approach for the determination of ng.l-1 amounts of steroid hormones in unidentified aqueous samples. Anal. Chim. Acta 586(1-2): 22-29. https://dx.doi.org/10.1016/j.aca.2006.08.048, more Noppe, H. (2006). Analytiek van hormoon verstorende stoffen in milieumatrices = Analytics of endocrine disrupting chemicals in environmental matrices. PhD Thesis. Universiteit Gent. Faculteit Diergeneeskunde: Gent. ISBN 978-90-5864-100-7. 153 pp., more Noppe, H. et al. (2006). Development and validation of an analytical method for detection of estrogens in water, in: Noppe, H. Analytiek van hormoon verstorende stoffen in milieumatrices = Analytics of endocrine disrupting chemicals in environmental matrices. pp. 21-41, more Noppe, H. et al. (2005). Development and validation of an analytical method for detection of estrogens in water. Anal. Bioanal. Chem. 382(1): 91-98. dx.doi.org/10.1007/s00216-005-3174-8, more Noppe, H. et al. (2005). Endocriene verstoringen in het Schelde estuarium (1) = Endocrine disruptors in the Scheldt estuary (1), in: Mees, J. et al. (Ed.) (2005). VLIZ Young Scientists' Day, Brugge, Belgium 25 February 2005: book of abstracts. VLIZ Special Publication, 20: pp. 50, more Dataset status: Completed Data type: Data Data origin: Research Metadatarecord created: 2004-05-10 Information last updated: 2017-11-17 | ||||
